The paper presents the results of ignition and thermal behavior for samples of high-energy materials (HEM) based on ammonium perchlorate (AP) and ammonium nitrate (AN), active binder and powders of Al, B, AlB2, and TiB2. A CO2 laser with a heat flux density range of 90-200 W/cm2 was used for studies of ignition. The activation energy and characteristics of ignition for the HEM samples were determined. Also, the ignition delay time and the surface temperature of the reaction layer during the heating and ignition for the HEM samples were determined. It was found that the complete replacement of micron-sized aluminum powder by amorphous boron in a HEM sample leads to a considerable decrease in the ignition delay time by a factor of 2.2-2.8 at the same heat flux density due to high chemical activity and the difference in the oxidation mechanisms of boron particles. The use of aluminum diboride in a HEM sample allows one to reduce the ignition delay time of a HEM sample by a factor of 1.7-2.2. The quasi-stationary ignition temperature is the same for the AlB2-based and AlB12-based HEM samples.
A tangent linear approximation of the ignition delay time. I: Sensitivity to rate parameters