Organothallium compounds. Reaction of phenylhydrazine with thallium(iii) oxide

I. F. Gun’kin

doi:10.1007/bf02495221

Organothallium compounds. VII. β-Diketonatobis(pentafluorophenyl)-thallium(III) compounds and their coordination derivatives

Australian Journal of Chemistry ◽

10.1071/ch9712519 ◽

1971 ◽

Vol 24 (12) ◽

pp. 2519 ◽

Cited By ~ 4

Author(s):

GB Deacon ◽

VN Garg

Keyword(s):

Molecular Weight ◽

Phosphine Oxide ◽

Spectroscopic Data ◽

Triphenyl Phosphine ◽

Organothallium Compounds ◽

Triphenyl Phosphine Oxide

The complexes (C6F5)2TlX [X = MeCOCHCOMe (acac), CF3COCHCOMe (tfac), CF8COCHCOCF3 (hfac), PhCOCHCOMe (bzac), PhCOCHCOPh (dbm), or quinolin-8- olate (oxinate or ox)], have been prepared by reactions between bromobis(pentafluorophenyl)thallium(III) and the appropriate sodium or thallous β-diketonates or sodium quinolin-8-olate, and react with equimolar amounts of 1,10-phenanthroline (phen) or 2,2?-bipyridyl (bipy) to give the complexes (C6F5)2- (phen or bipy)TlX (X = acac, tfac, or hfac), (C6F5)2(phen)TlX (X = bzac, dbm, or ox), but not (C6F5)2(bipy)TlX (X = bzac, dbm, or ox). On reaction with triphenyl- phosphine oxide or triphenylarsine oxide, the complexes (C6F5)2(Ph3PO or Ph3AsO)-TlX (X = acac, tfac, hfac, or dbm) and (C6F5)2Ph3AsOTl(ox) have been obtained. From conductance and molecular weight measurements and spectroscopic data, the complexes (C6F5)2TlX (except X = ox), (C6F5)2(Ph3PO or Ph3AsO)TlX, and (C6F5)2(phen or bipy)TlX, are considered to be monomeric with chelated β-diketonate or oxinate groups, and hence to contain four-, five-, and six-coordinate thallium respectively, whereas (C6F5)2Tl(ox) is considered to have an associated structure with bridging oxinate groups.

619. The chemistry of organothallium compounds. Part I. The preparations and properties of bis(pentafluorophenyl)thallium(III) compounds

Journal of the Chemical Society (Resumed) ◽

10.1039/jr9650003411 ◽

1965 ◽

pp. 3411 ◽

Cited By ~ 66

Author(s):

G. B. Deacon ◽

J. H. S. Green ◽

R. S. Nyholm

Keyword(s):

Organothallium Compounds

ChemInform Abstract: ORGANOTHALLIUM COMPOUNDS PART 10, THE FORMATION OF POLYFLUOROPHENYLTHALLIUM COMPOUNDS BY DESULPHINATION REACTIONS

Chemischer Informationsdienst ◽

10.1002/chin.197552313 ◽

1975 ◽

Vol 6 (52) ◽

pp. no-no

Author(s):

G. B. DEACON ◽

I. K. JOHNSON

Keyword(s):

Organothallium Compounds

Possibility of synthesizing organotin compounds by reduction of organothallium compounds with stannous salts

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science ◽

10.1007/bf00915853 ◽

1959 ◽

Vol 8 (4) ◽

pp. 617-619

Author(s):

A. N. Nesmeyanov ◽

A. E. Borisov ◽

N. V. Novikova

Keyword(s):

Organotin Compounds ◽

Organothallium Compounds

Scaled Hartree-Fock force field calculations for organothallium compounds: normal-mode analysis for TlCH3, Tl(CH3)2+, Tl(CH3)3, Tl(CH3)2Br, and Tl(CH3)4-

Organometallics ◽

10.1021/om00116a030 ◽

1990 ◽

Vol 9 (2) ◽

pp. 504-508 ◽

Cited By ~ 6

Author(s):

Peter Schwerdtfeger ◽

Graham A. Bowmaker ◽

Peter D. W. Boyd ◽

David C. Ware ◽

Penelope J. Brothers ◽

...

Keyword(s):

Force Field ◽

Normal Mode ◽

Normal Mode Analysis ◽

Mode Analysis ◽

Force Field Calculations ◽

Hartree Fock ◽

Organothallium Compounds

Nitroxide radical as a nuclear spin decoupling reagent. Application to carbon-13 nuclear magnetic resonance studies of organothallium compounds

Journal of the American Chemical Society ◽

10.1021/ja00469a099 ◽

1978 ◽

Vol 100 (1) ◽

pp. 354-356 ◽

Cited By ~ 14

Author(s):

Isao Morishima ◽

Toshiro Inubushi ◽

Sakae Uemura ◽

Haruo Miyoshi

Keyword(s):

Nuclear Magnetic Resonance ◽

Magnetic Resonance ◽

Nuclear Spin ◽

Nitroxide Radical ◽

Magnetic Resonance Studies ◽

Organothallium Compounds ◽

Nuclear Magnetic

Organothallium compounds XII NMR spectra of some polyfluorophenylthallium (III) compounds

Journal of Fluorine Chemistry ◽

10.1016/s0022-1139(00)81598-5 ◽

1978 ◽

Vol 11 (1) ◽

pp. 57-69 ◽

Cited By ~ 12

Author(s):

G.B. Deacon ◽

R.M. Slade ◽

D.G. Vince

Keyword(s):

Nmr Spectra ◽

Organothallium Compounds