Determination of trace impurities in rhodium metal by destructive and non-destructive neutron activation analysis

1976 ◽  
Vol 31 (1) ◽  
pp. 61-87 ◽  
Author(s):  
S. Sterliński ◽  
H. Maleszewska ◽  
R. Dybczyński
2000 ◽  
Vol 88 (3-4) ◽  
Author(s):  
Jamshed H. Zaidi ◽  
S. Waheed ◽  
Shujaat Ahmad

A radiochemical neutron activation analysis procedure has been developed and applied to investigate 40 major, minor, and trace impurities in iron-based alloy. A comparison of RNAA and INAA indicated a significant improvement in the detection limits. The extensive use of these alloys in the heavy mechanical industry, manufacturing of aircraft engines, nuclear applications, medical devices and chemical equipment requires their precise characterization. The concentration of iron in the iron-based alloy was found to be 86.7%, whereas Ca, Cr, K, Mg, Mn, V and W were the other constituents of the alloy, which constituted to around 12.89%. The rest of the elements were present in minor or trace levels. Most of the rare earth elements were also present in trace amounts.


The elemental compositions of archaeological artefacts, ancient and medieval coins, and metallic art objects have been determined by non-destructive neutron activation analysis. Examples are given of studies of prehistoric trade routes and cultural contacts based on the identification of the geologic origins of obsidian artefacts, of early economic systems based on the determination of debasement patterns in medieval Islamic and Western gold and silver coinage, the region of manufacture as well as authentication of ancient metallic art objects based on trace element analysis. Special procedures devised for performing these analyses are described.


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