Thermodynamic and kinetic studies on reversible liquid-phase Diels Alder reaction between maleic anhydride and 2-methyl furan

1994 ◽  
Vol 42 (2-3) ◽  
pp. 461-466 ◽  
Author(s):  
N. Balbi ◽  
B. Khoumeri
Keyword(s):  
Liquid Phase ◽  
Maleic Anhydride ◽  
Kinetic Studies ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction

scholarly journals KINETIC STUDIES ON THE HIGH-PRESSURE DIELS–ALDER REACTION OF TROPONE WITH MALEIC ANHYDRIDE

1984 ◽  
Vol 13 (10) ◽  
pp. 1855-1858 ◽  
Author(s):  
Hitoshi Takeshita ◽  
Shigeru Sugiyama ◽  
Toshihide Hatsui
Keyword(s):  
High Pressure ◽  
Maleic Anhydride ◽  
Kinetic Studies ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction

Hetero-Diels-Alder Reactions of Enaminothione with Electrophilic Olefins. Synthesis of 2-Furyl Substituted 2H-Thiopyrans

2002 ◽  
Vol 57 (6) ◽  
pp. 637-644 ◽  
Author(s):  
Krystyna Bogdanowicz-Szwed ◽  
Artur Budzowski
Keyword(s):  
Acetic Acid ◽  
Maleic Anhydride ◽  
Acetic Anhydride ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diethyl Maleate ◽  
Diels Alder Reaction

AbstractThe hetero-Diels-Alder reaction of 1-(2-furyl)-3-(dimethylamino)-2-propene-1-thione (diene) with maleic and fumaric acids, and β-nitrostyrenes yielded 3,4-dihydro-2H-thiopyran derivatives. Treatment of some of those cycloadducts with acetic acid caused elimination of dimethylamine yielding stable 2H-thiopyrans. Reaction of the diene with maleic anhydride furnished a cycloadduct which underwent spontaneous rearrangement to form an N,N-dimethylamide derivative. Cycloadditions of the diene to maleimide, N-phenylmaleimide, diethyl maleate, fumarate and butenolide, carried out in the presence of acetic anhydride,were followed by elimination of dimethylamine, afforded stable 2H-thiopyran derivatives.

Reply to Comment on “Kinetics of a Diels−Alder Reaction of Maleic Anhydride and Isoprene in Supercritical CO2”

2003 ◽  
Vol 107 (43) ◽  
pp. 9249-9249 ◽  
Author(s):  
Evgeni M. Glebov ◽  
Larisa G. Krishtopa ◽  
Victor Stepanov ◽  
Lev N. Krasnoperov
Keyword(s):  
Maleic Anhydride ◽  
Supercritical Co2 ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction ◽  
Kinetics Of

Synthetic and kinetic studies of substituent effects in the furan intramolecular Diels-Alder reaction

Tetrahedron ◽  
1994 ◽  
Vol 50 (23) ◽  
pp. 6767-6782 ◽  
Author(s):  
Brian J. McNelis ◽  
Daniel D. Sternbach ◽  
Andrew T. MacPhail
Keyword(s):  
Substituent Effects ◽  
Kinetic Studies ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction

High pressure organic chemistry. Part 17. Diels–Alder reaction of methyl palustrate with maleic anhydride and N-phenylmaleimide

1993 ◽  
pp. 2773-2776 ◽  
Author(s):  
Hiyoshizo Kotsuki ◽  
Masanori Kataoka ◽  
Kohtaro Matsuo ◽  
Shigeru Suetomo ◽  
Motoo Shiroc ◽  
...  
Keyword(s):  
Organic Chemistry ◽  
High Pressure ◽  
Maleic Anhydride ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction

Vinylindenes and Some Heteroanalogs in the Diels-Alder Reaction. X. Dibenzofurans From 3-Vinylbenzofurans

1991 ◽  
Vol 44 (8) ◽  
pp. 1085 ◽  
Author(s):  
JR Pearson ◽  
QN Porter
Keyword(s):  
Maleic Anhydride ◽  
Alder Reaction ◽  
Diels Alder ◽  
Dimethyl Acetylenedicarboxylate ◽  
Diels Alder Reaction

3-Vinylbenzofuran, 3-isopropenylbenzofuran and 2-methyl-3-vinylbenzofuran give normal [4π+2π] adducts with ethenetetracarbonitrile, accompanied, in the case of the last named diene, by the isomeric cyclobutane. Normal adducts also result from these dienes and 4-phenyl-1,2,4-triazoline-3,5-dione, and from 3-vinylbenzofuran and both maleic anhydride and N- phenylmaleimide. 3-Vinylbenzofuran gives the rearranged adduct dimethyl 1,2-dihydrodibenzofuran-3,4-dicarboxylate with dimethyl acetylenedicarboxylate.

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