Photoinduced electron transfer from naphthalenes to dicyanoethenes and subsequent radical ion processes studied by time resolved CIDNP

1993 ◽  
Vol 5 (2) ◽  
pp. 127-150 ◽  
Author(s):  
E. Schaffner ◽  
M. Kweton ◽  
P. Vesel ◽  
H. Fischer
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Time Resolved

scholarly journals Electron self-exchange activation parameters of diethyl sulfide and tetrahydrothiophene

2013 ◽  
Vol 9 ◽  
pp. 1448-1454
Author(s):  
Martin Goez ◽  
Martin Vogtherr
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Nuclear Polarization ◽  
Activation Barrier ◽  
Activation Parameters ◽  
Radical Cations ◽  
Free Energies ◽  
Time Resolved ◽  
Diethyl Sulfide ◽  
Chemically Induced

Electron transfer between the title compounds and their radical cations, which were generated by photoinduced electron transfer from the sulfides to excited 2,4,6-triphenylpyrylium cations, was investigated by time-resolved measurements of chemically induced dynamic nuclear polarization (CIDNP) in acetonitrile. The strongly negative activation entropies provide evidence for an associative–dissociative electron exchange involving dimeric radical cations. Despite this mechanistic complication, the free energies of activation were found to be well reproduced by the Marcus theory of electron transfer, with the activation barrier still dominated by solvent reorganization.

Time-Resolved Spectroscopy of Photoinduced Electron Transfer in Dinuclear and Tetranuclear Fe/Co Prussian Blue Analogues

2020 ◽  
Vol 60 (1) ◽  
pp. 449-459
Author(s):  
Jennifer Zimara ◽  
Hendrik Stevens ◽  
Rainer Oswald ◽  
Serhiy Demeshko ◽  
Sebastian Dechert ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Prussian Blue ◽  
Photoinduced Electron Transfer ◽  
Time Resolved ◽  
Time Resolved Spectroscopy ◽  
Prussian Blue Analogues
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