Synthesis, physicochemical investigation and biological studies of Zinc(II) complexes with 1,2,4-triazole Schiff bases

2009 ◽  
Vol 6 (2) ◽  
pp. 259-270 ◽  
Author(s):  
G. B. Bagihalli ◽  
S. A. Patil ◽  
P. S. Badami
2019 ◽  
Vol 1175 ◽  
pp. 624-631 ◽  
Author(s):  
Mirela-Fernanda Zaltariov ◽  
Mihaela Avadanei ◽  
Mihaela Balan ◽  
Dragos Peptanariu ◽  
Nicoleta Vornicu ◽  
...  

Author(s):  
Mallikarjun S. Yadawe ◽  
Shrishila N. Unki ◽  
Sangamesh A. Patil

Some lanthanum(III) complexes have been synthesized by reacting lanthanum(III) metal salt with Schiff bases derived from 3-substituted-4-amino-5-mercapto-1,2,4-triazole and glyoxal/biacetyl/benzyl. All these complexes are not soluble in common organic solvents. However sparingly soluble in DMF and DMSO. The chemical analysis of the complexes confirmed to the stoichiometry of the type La(III)LNO3·H2O. La(III)LCl·H2O and La(III)LNCS·H2O respectively. The chelation of the complexes has been proposed in the light of analytical, spectral studies. The measured molar conductance values indicate that, the complexes are non-electrolytes. The Schiff bases and their complexes have been screened for their antibacterial and antifungal activities. The results of these studies show the metal complexes to be more antibacterial and antifungal as compared to the uncomplexed coumarins.


2008 ◽  
Vol 2008 ◽  
pp. 1-7 ◽  
Author(s):  
A. P. Mishra ◽  
Monika Soni

New bidentate or tridentate Schiff bases and their VO(II) and Co(II) complexes formed by the condensation of methyl isobutyl ketone with nicotinamide (mna)/2-amino-4-chlorophenol (map) and 2-hydroxy acetophenone with nicotinamide (han)/isoniazide (hai). Physicochemical characterization has been carried out to determine the structure of the complexes. The FAB mass and thermal data show degradation pattern of the complexes. XRD analysis reveals that all the studied complexes crystallize as tetragonal crystal system. Some of the complexes have been screened for their antimicrobial activity by the well diffusion technique using DMSO as solvent on different species of pathogenic bacteria/fungi, that is, E. coli, S. aureus, S. fecalis, A. niger, T. polysporum, and their antimicrobial potency have been discussed. It has been found that all the complexes are antimicrobially active and show higher activity than the free ligand. Metal chelation affects significantly the antimicrobial/bioactive behavior of the organic ligands.


2013 ◽  
Vol 66 (2) ◽  
pp. 274-286 ◽  
Author(s):  
Vijay Kumar Chityala ◽  
K. Sathish Kumar ◽  
N.J.P. Subhashini ◽  
Pallepogu Raghavaiah

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