Fractions, Contamination and Health Risk of Cadmium in Alpine Soils on the Gongga Mountain, Eastern Tibetan Plateau

The concentrations of Pb and Cd in the needles and twigs of fir and spruce collected from 26 sites in the Eastern Tibetan Plateau were measured and analyzed in this study. The mean concentrations of Cd and Pb were 0.034 and 1.291 mg/kg, respectively, in the needles and 0.101 and 2.511 mg/kg, respectively, in the twigs. These concentrations increased significantly with needle and twig age and peaked at 5 years. The twigs were significantly enriched in Pb and Cd compared with the needles. The spatial distributions of Pb and Cd were determined using the inverse-distance-weighted spatial interpolation method on the basis of the mean concentration of the elements in the needles and twigs from each site. The highest concentrations of Pb and Cd in twigs and needles were found in Yunnan Province and Gongga Mountain. They showed a tendency to decline from Yunnan Province to the northern direction, as well as from Gongga Mountain to the western area. Principal component analysis showed that Pb and Cd originated from the anthropogenic activities in this area. The mining activities and climatic factors may be the main sources of Pb and Cd in this area. Combining the HYSPLIT (The Hybrid Single-Particle Lagrangian Integrated Trajectory) model and PCA, the results implied that exterior Pb and Cd sources from Southeast Asia and the eastern developed cities in China can infiltrate the ecosystem through long-range transportation and accumulate in timberline forests, with atmospheric deposition in the Eastern Tibetan Plateau. This plateau suffers from severe Pb pollution but slight Cd contamination.

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Distribution of preferential flow pathways and solute transfer along the Hailuogou Glacier Chronosequence on the Eastern Tibetan Plateau

10.5194/egusphere-egu2020-19059 ◽

2020 ◽

Author(s):

Jian-Hong Liang ◽

Yan-Hong Wu ◽

Georg Guggenberger

Keyword(s):

Tibetan Plateau ◽

Preferential Flow ◽

Coniferous Forest ◽

Eastern Tibetan Plateau ◽

Forest Types ◽

Broadleaf Forest ◽

Solute Transfer ◽

Gongga Mountain ◽

Flow Pathways ◽

Preferential Flow Pathways

Preferential flow pathways (PFPs) are key contributors for the ecological status of the hydrosphere in high mountain environments, as the precipitation will transfer to PFPs with rapid solute transport from soil to groundwater. This particularly refers to nutrient allocation from soils to groundwater and surface waters.To understand the effects of the pedogenesis and forest types on the soil PFPs, the soil preferential flow was studied by in situ dye tracing image analysis and elemental chemical analysis at the Hailuogou glacier chronosequence, Gongga Mountain on the eastern Tibetan Plateau. A soil chronosequence and a vegetation primary succession following the retreat of the Hailuogou glacier has been forming since ~1890. Three sites representing different exposure age (45, 85 and 125 years) in the Hailuogou glacier retreat area chronosequence and two sites typical forest lands (deciduous broadleaf forest and coniferous forest) were selected to carry out a brilliant blue dyeing experiment to visualize the distribution of water infiltration in soil.The tracer-infiltration patterns were parameterized by dye coverage (DC), preferential flow fraction (PF), length index (Li) and the variation coefficient of DC in the PFPs (CV). Furthermore, the distribution of PFPs, transported solute of soil PFPs was analyzed including Hailuogou glacier chronosequence and vegetation succession.According to the comparison of PFPs parameters, soil PFPs at the 125-year-old site extremely more developed than that at the younger site due to the fracture development between rock and soil on the process of soil development. The soil PFPs under broadleaf forest is more pronounced than that in coniferous forest soils, largely depending on the different root system.In general, PFPs in Gongga Mountain were important contributors to the potential translocation of bioavailable inorganic P (PBPi) and organic P translocation to the hydrosphere. The elements transported with PFPs could be divided into three categories, reactive, conservative, and both reacted and conservative elements for the concentration of the elements remain in the PFPs. The results indicated that Mg and Al are the reactive elements, while Na, K, Ca and Mn are the conservative elements in the PFPs. Iron is both reacted and conservative element in the PFPs.&#160;Zn, Na, K, Mg, PBPi, had a significant correlation with the variation coefficient of DC in the PFPs (CV).The results highlight the effects of the pedogenesis and forest types on the distribution of PFPs and solute transfer. Preferential flow contributes largely to elements flow at the Hailuogou glacier chronosequence and vegetation succession, Gongga Mountain.The financial support of this work was obtained from National Natural Science Foundation of China (Grant No. 41272220) and Natural Scientifc Foundation for Young Scientists of Guangxi Zhuang Autonomous Region of China (Grant No. 2017GXNSFBA198162). The first author was financially supported by the Sino-German (CSC-DAAD) Postdoc Scholarship Program funded by China Scholarship Council (CSC) and Deutscher Akademischer Austausch Dienst (DAAD).

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