Ionic liquids as gas chromatographic stationary phases: how can they change food and natural product analyses?

2019 ◽  
Vol 412 (1) ◽  
pp. 17-25 ◽  
Author(s):  
Cecilia Cagliero ◽  
Carlo Bicchi
2021 ◽  
Vol 17 ◽  
Author(s):  
Giuseppe Maria Merone ◽  
Angela Tartaglia ◽  
Enrica Rosato ◽  
Cristian D’Ovidio ◽  
Abuzar Kabir ◽  
...  

Background: Ionic liquids (ILs) are a unique class of compounds consisting exclusively of cations and anions that possess distinctive properties such as low volatility, high thermal stability, miscibility with water and organic solvents, electrolytic conductivity and non-flammability. Ionic liquids have been defined as "design solvents", because it is possible to modify their physical and chemical properties by appropriately choosing cations and anions, in order to meet the specific characteristics based on their potential application. Introduction: Due of their tunable nature and properties, ILs are considered as the perfect candidates for numerous applications in analytical chemistry including sample preparation, stationary phases in liquid or gas chromatography, additives in capillary electrophoresis, or in mass spectrometry for spectral and electrochemical analysis. In the last years, the number of publications regarding ILs has rapidly increased, highlighting the broad applications of these compounds in various fields of analytical chemistry. Results: This review first described the main physico-chemical characteristics of ionic liquids, and subsequently reported the various applications in different subdisciplines of analytical chemistry, including the extraction procedure and separation techniques. Furthermore, in each paragraph the most recent applications of ionic liquids in the food, environmental, biological, etc. fields have been described. Conclusion: Overall, the topic discussed highlights the key role of ionic liquids in analytical chemistry, giving hints for their future applications in chemistry but also in biology and medicine.


2019 ◽  
Vol 102 (1) ◽  
pp. 3-22
Author(s):  
Tomasz Tuzimski ◽  
Anna Petruczynik

Abstract Ionic liquids (ILs) are a class of unique substances composed purely by cation and anions. Because of the unique properties of ILs (e.g., electric conductivity, low volatility, thermostability, and tenability), their use has attracted considerable interest, including an increasing number of publications on their use in analytical separation techniques. ILs applied as extraction solvents in liquid–liquid extraction methods and promote interactions between the analyte and solvent because of their unique chemical functional groups. In solid-phase extraction, ILs are usually used for the modification of stationary phases. ILs in LC are applied as mobile phase additives to obtain a better peak shape and high system efficiency for the analysis of ionic, especially basic, compounds. This review highlights some of the applications of ILs to extraction and analysis by LC of xenobiotics in food, environmental, and biological samples.


2004 ◽  
Vol 76 (22) ◽  
pp. 6819-6822 ◽  
Author(s):  
Jie Ding ◽  
Thomas Welton ◽  
Daniel W. Armstrong

Crystals ◽  
2017 ◽  
Vol 7 (10) ◽  
pp. 284 ◽  
Author(s):  
Ji-Hun An ◽  
Alice Kiyonga ◽  
Woojin Yoon ◽  
Minho Park ◽  
Changjin Lim ◽  
...  

2011 ◽  
Vol 74 (9-10) ◽  
pp. 717-724 ◽  
Author(s):  
Qingquan Wei ◽  
Meiling Qi ◽  
Hanxue Yang ◽  
Ruonong Fu

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