DFT analysis of the interaction between Hg2+ and monodentate neutral ligands using NBO, EDA, and QTAIM

2020 ◽  
Vol 26 (6) ◽  
Author(s):  
Victor Hugo Malamace da Silva ◽  
José Walkimar de Mesquita Carneiro ◽  
Leonardo Moreira da Costa ◽  
Glaucio Braga Ferreira
Keyword(s):  
Neutral Ligands

Syntheses, Structures, and Characterizations of Four New Silver(I) Sulfonate Coordination Polymers with Neutral Ligands

2006 ◽  
Vol 6 (1) ◽  
pp. 209-215 ◽  
Author(s):  
Fang-Fang Li ◽  
Jian-Fang Ma ◽  
Shu-Yan Song ◽  
Jin Yang ◽  
Heng-Qing Jia ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Neutral Ligands

scholarly journals Potassium Channel Block by a Tripartite Complex of Neutral Ligands with a Potassium Ion

2010 ◽  
Vol 24 (S1) ◽  
Author(s):  
Pavel I Zimin ◽  
Bojan Garic ◽  
Heike Wulff ◽  
Boris S Zhorov
Keyword(s):  
Potassium Channel ◽  
Potassium Ion ◽  
Channel Block ◽  
Neutral Ligands

Spectral luminescence studies of uranyl nitrate crystals with neutral ligands

1996 ◽  
Vol 63 (4) ◽  
pp. 557-560
Author(s):  
A. P. Zazhogin ◽  
A. A. Zazhogin ◽  
A. I. Komyak ◽  
A. I. Serafimovich
Keyword(s):  
Uranyl Nitrate ◽  
Neutral Ligands ◽  
Spectral Luminescence

Modulating extraction and retention of fluorinated β-diketonate metal complexes in perfluorocarbons through the use of non-fluorinated neutral ligands

2021 ◽  
Vol 8 (20) ◽  
pp. 4488-4496
Author(s):  
Tyler L. King ◽  
Orhi Esarte Palomero ◽  
Dawson A. Grimes ◽  
Sean T. Goralski ◽  
Richard A. Jones ◽  
...  
Keyword(s):  
Medical Imaging ◽  
Metal Ions ◽  
Metal Complexes ◽  
Synergistic Extraction ◽  
Donor Ligands ◽  
Nuclear Fuels ◽  
Nitrogen Donor Ligands ◽  
Nitrogen Donor ◽  
Neutral Ligands

Extraction of metal ions into perfluorocarbon solvent with a fluorinated acac ligand is described as well as synergistic extraction with neutral nitrogen donor ligands. Applications include catalysis, nuclear fuels reprocessing, and medical imaging.

scholarly journals Stabilizing Magnesium Hydride Complexes with Neutral Ligands

2019 ◽  
Vol 2019 (41) ◽  
pp. 4433-4439 ◽  
Author(s):  
Michael Wiesinger ◽  
Brant Maitland ◽  
Holger Elsen ◽  
Jürgen Pahl ◽  
Sjoerd Harder
Keyword(s):  
Magnesium Hydride ◽  
Hydride Complexes ◽  
Neutral Ligands

[Fe4S4I2(C6H10(NHCSNHMe)2)]: ein neutraler Eisen-Schwefel-Cluster mit zweizähnigem Liganden / [Fe4S4I2(C6H10(NHCSNHMe)2)]: A Neutral Iron-Sulfur Cluster with a Bidentate Ligand

1992 ◽  
Vol 47 (9) ◽  
pp. 1266-1270 ◽  
Author(s):  
Siegfried Pohl ◽  
Ulrich Bierbach
Keyword(s):  
Solid State ◽  
Bidentate Ligand ◽  
Striking Feature ◽  
Monoclinic Space Group ◽  
Thiourea Derivative ◽  
Iron Sulfur Cluster ◽  
Sulfur Cluster ◽  
Space Group ◽  
Iron Sulfur ◽  
Neutral Ligands

The reaction of [Fe4S4I2(SC(NMe2)2)2] with racemic trans-1,2-bis(3-methylthioureido)-cyclohexane in tetrahydrofuran (thf) yields [Fe4S4I2(C6H10(NHCSNHMe)2)] · 4 thf (2). 2 crystallizes in the monoclinic space group C 2/c with a = 1471.7(2), b = 1329.7(2), c = 2339.3(3) pm, β = 107.70(1), V = 4362.3 × 106 pm3, Z = 4, R = 0.057. The cluster exhibits C2 symmetry in the solid state. The replacement of the monodentate neutral ligands results in a cluster in which the bifunctional thiourea derivative bridges two different iron sites of the slightly compressed [Fe4S4] core. The most striking feature are the differences of the Fe–Fe distances which are 269.8 pm between thiourea coordinated atoms and 280.7 pm between Fe atoms with iodide ligation. The Fe–S thiourea distance was found to be 229.3 pm.

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