scholarly journals Recoverable acrylamide-vinylamine copolymer immobilized TEMPO mediated oxidation of cellulose with good catalytic performance and low cellulose degradation

Cellulose ◽  
2021 ◽  
Author(s):  
Tingting Sun ◽  
Huimin Wang ◽  
Jiaye Liu ◽  
Xiaomeng Chu ◽  
Xuteng Xing ◽  
...  
Keyword(s):  
Cellulose Degradation ◽  
Catalytic Performance ◽  
Mediated Oxidation

scholarly journals Recoverable acrylamide-vinylamine copolymer immobilized TEMPO mediated oxidation of cellulose with good catalytic performance and low cellulose degradation

2021 ◽  
Author(s):  
Tingting Sun ◽  
Huimin Wang ◽  
Jiaye Liu ◽  
Xiaomeng Chu ◽  
Xuteng Xing ◽  
...  
Keyword(s):  
Selective Oxidation ◽  
Cellulose Degradation ◽  
Catalytic Performance ◽  
Reduction Reaction ◽  
Hydroxyl Groups ◽  
Oxidized Cellulose ◽  
Carboxyl Content ◽  
Amine Groups ◽  
Degradation Degree ◽  
Mediated Oxidation

Abstract In this work, a recoverable acrylamide-vinylamine copolymer immobilized TEMPO (P(AM-co-VAm)-T) catalyst for selective oxidation of cellulose with good catalytic performance and low cellulose degradation was developed. Firstly, the acrylamide-vinylamine copolymer (P(AM-co-VAm)) was prepared by Hofmann degradation of polyacrylamide (PAM). Then, the condensation reduction reaction between amine groups of P(AM-co-VAm) and carbonyl groups of 4-oxo-TEMPO yielded P(AM-co-VAm)-T. P(AM-co-VAm)-T was used as a catalyst for selective oxidation of C6 primary hydroxyl groups of cellulose to carboxyl groups. The carboxyl content of obtained oxidized cellulose was up to 1.114 mmol/g, which was equivalent to 76% of the free TEMPO level. This macromolecular catalyst was easily recycled and the recycling performance was excellent. Interestingly, it was found that P(AM-co-VAm)-T could effectively reduce the degradation of oxidized cellulose. The corresponding degradation degree was 21%-27%, which was much lower than the degradation degree of free TEMPO (61%-66%) and other macromolecular TEMPO catalysts, such as polyacrylic acid immobilized-TEMPO (41%-53%) and polyamidoamine supported TEMPO (28%-44%). P(AM-co-VAm)-T with positive charge and suitable size could effectively inhibit the formation of C6 aldehydes and C2/C3 ketones, which was the main reason that it could significantly inhibit cellulose degradation.

scholarly journals Recoverable Water-soluble Polyethylene Glycol-immobilized N-hydroxyphthalimide Mediated Oxidation of Cellulose in the Presence of NaBr and NaClO

2021 ◽  
Author(s):  
Huimin Wang ◽  
Xiaoying Wang ◽  
Tingting Sun ◽  
Peixin Li ◽  
Xiaomeng Chu ◽  
...  
Keyword(s):  
Polyethylene Glycol ◽  
Water Solubility ◽  
Cellulose Degradation ◽  
Catalytic Performance ◽  
Water Soluble ◽  
Resonance Spectroscopy ◽  
Oxidized Cellulose ◽  
Carboxyl Content ◽  
Selective Catalytic Oxidation ◽  
Mediated Oxidation

Abstract As a highly efficient nitroxide radical catalyst for selective catalytic oxidation of cellulose, N-hydroxyphthalimide (NHPI) has attracted much attention because of its low price and light cellulose degradation. However, NHPI is insoluble in water and is difficult to recycle because of its small molecular weight. To address the above issues, the water-soluble polyethylene glycol (PEG)-immobilized NHPI catalyst (PEG-NHPI) was designed and prepared in this work. Fourier transform infrared spectroscopy (FT-IR), nuclear magnetic resonance spectroscopy (NMR), gel permeation chromatography (GPC) and UV-vis light spectroscopy were used to characterize PEG-NHPI. The results showed that PEG-NHPI catalysts with good water solubility and adjustable NHPI loading amounts were successfully synthesized. Using NaBr as promoter and NaClO as oxidant, PEG-NHPI mediated oxidation of cellulose was carried out and good catalytic performance was found. The catalytic performance of PEG-NHPI mediated oxidation of cellulose in water was higher than that in acetonitrile-water. The carboxyl content of PEG-NHPI oxidized cellulose could reach the level of free NHPI oxidized cellulose, and was equivalent to 68% of 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO) oxidized cellulose, while the degradation degree of cellulose was greatly reduced by more than 40%. The catalytic performance did not decrease significantly after six oxidation cycles. The structure of recycled PEG-NHPI was not changed. These results indicated that immobilizing NHPI onto PEG can achieve the unification of high catalytic performance and good recyclability.

The design and catalytic performance of molybdenum active sites on an MCM-41 framework for the aerobic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran

2019 ◽  
Vol 9 (3) ◽  
pp. 811-821 ◽  
Author(s):  
Zhao-Meng Wang ◽  
Li-Juan Liu ◽  
Bo Xiang ◽  
Yue Wang ◽  
Ya-Jing Lyu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Active Sites ◽  
Aerobic Oxidation ◽  
Catalytic Performance ◽  
Mcm 41

The catalytic activity decreases as –(SiO)3Mo(OH)(O) > –(SiO)2Mo(O)2 > –(O)4–MoO.

Optimizing electron density of nickel sulfide electrocatalysts through sulfur vacancy engineering for alkaline hydrogen evolution

2020 ◽  
Vol 8 (35) ◽  
pp. 18207-18214
Author(s):  
Dongbo Jia ◽  
Lili Han ◽  
Ying Li ◽  
Wenjun He ◽  
Caichi Liu ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Electron Density ◽  
Rational Design ◽  
Nickel Sulfide ◽  
Catalytic Performance ◽  
Sulfide Catalysts ◽  
Sulfur Vacancy

A novel, rational design for porous S-vacancy nickel sulfide catalysts with remarkable catalytic performance for alkaline HER.

Catalytic Resonance Theory: Parallel Reaction Pathway Control

2019 ◽  
Author(s):  
M. Alexander Ardagh ◽  
Manish Shetty ◽  
Anatoliy Kuznetsov ◽  
Qi Zhang ◽  
Phillip Christopher ◽  
...  
Keyword(s):  
Chemical Reactions ◽  
Active Site ◽  
Active Sites ◽  
Reaction Pathway ◽  
Control Strategies ◽  
Oscillation Amplitude ◽  
Catalytic Performance ◽  
Parallel Reaction ◽  
Resonance Theory ◽  
Static Conditions

Catalytic enhancement of chemical reactions via heterogeneous materials occurs through stabilization of transition states at designed active sites, but dramatically greater rate acceleration on that same active site is achieved when the surface intermediates oscillate in binding energy. The applied oscillation amplitude and frequency can accelerate reactions orders of magnitude above the catalytic rates of static systems, provided the active site dynamics are tuned to the natural frequencies of the surface chemistry. In this work, differences in the characteristics of parallel reactions are exploited via selective application of active site dynamics (0 < ΔU < 1.0 eV amplitude, 10<sup>-6</sup> < f < 10<sup>4</sup> Hz frequency) to control the extent of competing reactions occurring on the shared catalytic surface. Simulation of multiple parallel reaction systems with broad range of variation in chemical parameters revealed that parallel chemistries are highly tunable in selectivity between either pure product, even when specific products are not selectively produced under static conditions. Two mechanisms leading to dynamic selectivity control were identified: (i) surface thermodynamic control of one product species under strong binding conditions, or (ii) catalytic resonance of the kinetics of one reaction over the other. These dynamic parallel pathway control strategies applied to a host of chemical conditions indicate significant potential for improving the catalytic performance of many important industrial chemical reactions beyond their existing static performance.

Fabrication and Excellent Catalytic Performance of Three-dimensional Ordered Mesoporous Molybdenum Oxides

2014 ◽  
Vol 29 (2) ◽  
pp. 124-130 ◽  
Author(s):  
Yu-Cheng DU ◽  
Guang-Wei ZHENG ◽  
Qi MENG ◽  
Li-Ping WANG ◽  
Hai-Guang FAN ◽  
...  
Keyword(s):  
Three Dimensional ◽  
Catalytic Performance ◽  
Molybdenum Oxides ◽  
Ordered Mesoporous ◽  
Excellent Catalytic Performance

Preparation of CeO2-ZrO2-Al2O3 and Catalytic Performance of Palladium-Based Three-Way Catalyst

2010 ◽  
Vol 31 (4) ◽  
pp. 429-434
Author(s):  
Ming ZHAO ◽  
Hairong WANG ◽  
Shanhu CHEN ◽  
Yanling YAO ◽  
Maochu GONG ◽  
...  
Keyword(s):  
Catalytic Performance ◽  
Three Way Catalyst

Effect of Supports on Catalytic Performance of Nickel-Based Catalyst for Methanation

2014 ◽  
Vol 32 (8) ◽  
pp. 1400-1404
Author(s):  
Xia LI ◽  
Xiazhen YANG ◽  
Haodong TANG ◽  
Huazhang LIU
Keyword(s):  
Catalytic Performance

Preparation of Cu-Mn/Zr-Ce-SBA-15 Catalyst with Short Mesochannels and Its Catalytic Performance for Toluene Combustion

2014 ◽  
Vol 32 (6) ◽  
pp. 1069-1075
Author(s):  
Jinfang YUAN ◽  
Jiansheng LI ◽  
Fang WANG ◽  
Xiuyun SUN ◽  
Jinyou SHEN ◽  
...  
Keyword(s):  
Catalytic Performance
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