Effect of multi-walled carbon nanotubes on mechanical and rheological properties of poly(trimethylene terephthalate)

2014 ◽  
Vol 49 (10) ◽  
pp. 3839-3846 ◽  
Author(s):  
Anju Gupta ◽  
Veena Choudhary
2021 ◽  
pp. 1-44
Author(s):  
Yunxiao Liu ◽  
Jiahang Zhang ◽  
Yinyin Chi

In this study, three different diameters of multi-walled carbon nanotubes (MWCNTs) dispersed by polyvinyl pyrrolidone (PVP) were used to reinforce superfine cement grouting materials. The effect of MWCNTs and polyvinyl pyrrolidone (PVP) on the rheological properties of grouting material were accordingly studied. It was found that the yield stress (τ0) and plastic viscosity (η) were slightly decreased when PVP content was low and increased when the PVP content increased. The effect of MWCNT diameter on τ0 was not found to be clear but was more significant on η. The smaller MWCNT diameter was, the more quickly η increase. It was also found that the thixotropic ring area was increased as the MWCNTs content increased. The addition of PVP and MWCNTs caused an increase in the number of entanglement points in different scales, which was the main reason for the viscosity and thixotropy increase. Therefore, the rheological properties of superfine cement grouting material should be adjusted when MWCNTs were added as a reinforcing component. Due to the wrapping of PVP on cement particles which isolates the contacting part between the water and the cement particles, it slows down the cement's hydration rate thus slows down the fluidity loss of the slurry.


Polymer ◽  
2014 ◽  
Vol 55 (16) ◽  
pp. 3758-3769 ◽  
Author(s):  
Dimitrios G. Papageorgiou ◽  
Lazaros Tzounis ◽  
George Z. Papageorgiou ◽  
Dimitrios N. Bikiaris ◽  
Konstantinos Chrissafis

2018 ◽  
Vol 189 ◽  
pp. 947-954 ◽  
Author(s):  
Dainius Leonavičius ◽  
Ina Pundienė ◽  
Giedrius Girskas ◽  
Jolanta Pranckevičienė ◽  
Modestas Kligys ◽  
...  

Fluids ◽  
2020 ◽  
Vol 5 (4) ◽  
pp. 169
Author(s):  
Gintautas Skripkiunas ◽  
Ekaterina Karpova ◽  
Joana Bendoraitiene ◽  
Irmantas Barauskas

In this study, the rheological properties of cement paste modified by a suspension containing both multi-walled carbon nanotubes (MWCNT) and carboxymethyl cellulose (CMC) (MWCNT/CMC suspension) with different types of plasticising admixtures (Pl), such as lignosulphonate (LS), sulfonated naphthalene formaldehyde condensate (NF), and polycarboxylate ether (PCE) were evaluated. The increase in yield stress and plastic viscosity up to 20% was established in the case of the modification of cement-based mixtures by MWCNT in the dosage up to 0.24% by weight of cement (bwoc) without Pl and with LS and NF. The complex modification of cement paste by MWCNT and PCE increases the yield stress and plastic viscosity from the MWCNT dosage of 0.06% and 0.015% bwoc, respectively. The yield stress and plastic viscosity of cement paste with PCE enhanced by 265% and 107%, respectively, in a MWCNT dosage of 0.12% bwoc. MWCNT do not have a significant influence on the flow behaviour index of cement paste; however, in the case of usage of PCE, the shear thickening effect decreased from a MWCNT dosage of 0.03% bwoc. The significant reduction in the volume coefficient of water bleeding by 99, 100, and 83% was obtained with LS, NF, and PCE, respectively, with an increase in MWCNT dosage up to 0.24% bwoc.


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