Reduction kinetics of NiO–YSZ composite for application in solid oxide fuel cell

2009 ◽  
Vol 97 (1) ◽  
pp. 303-308 ◽  
Author(s):  
W. K. Yoshito ◽  
J. R. Matos ◽  
V. Ussui ◽  
D. R. R. Lazar ◽  
J. O. A. Paschoal
Author(s):  
Christoph Riedl ◽  
Matthäus Siebenhofer ◽  
Andreas Nenning ◽  
Gernot Friedbacher ◽  
Maximilian Weiss ◽  
...  

Accelerating the oxygen reduction kinetics of solid oxide fuel cell (SOFC) cathodes is crucial to improve their efficiency and thus to provide the basis for an economically feasible application of...


2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
D. Mogensen ◽  
J.-D. Grunwaldt ◽  
P. V. Hendriksen ◽  
J. U. Nielsen ◽  
K. Dam-Johansen

The kinetics of catalytic steam reforming of methane over an Ni-YSZ anode of a solid oxide fuel cell (SOFC) have been investigated with the cell placed in a stack configuration. In order to decrease the degree of conversion, a single cell stack with reduced area was used. Measurements were performed in the temperature range 600–800°C and the partial pressures of all reactants and products were varied. The obtained rates could be well fitted with a power law expression (r ∝PCH40.7). A simple model is presented which is capable of predicting the methane conversion in a stack configuration from intrinsic kinetics of the anode support material. The predictions are compared with the stack measurements presented here, and good agreement is observed.


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