scholarly journals RETRACTED ARTICLE: Preparation of highly active ruthenium based catalysts and performance comparison of Ru catalyst and iron catalyst for ammonia synthesis

2011 ◽  
Vol 104 (1) ◽  
pp. 249-249
Author(s):  
Chonggen Pan ◽  
Ying Li ◽  
Huazhang Liu
2019 ◽  
Author(s):  
Katsutoshi Sato ◽  
Shin-ichiro Miyahara ◽  
Yuta Ogura ◽  
Kotoko Tsujimaru ◽  
Yuichiro Wada ◽  
...  

<p>To mitigate global problems related to energy and global warming, it is helpful to develop an ammonia synthesis process using catalysts that are highly active under mild conditions. Here we show that the ammonia synthesis activity of Ru/Ba/LaCeO<i><sub>x</sub></i> pre-reduced at 700 °C is the highest reported among oxide-supported Ru catalysts. Our results indicate that low crystalline oxygen-deficient composite oxides, which include Ba<sup>2+</sup>, Ce<sup>3+</sup> and La<sup>3+</sup>, with strong electron-donating ability, accumulate on Ru particles and thus promote N≡N bond cleavage, which is the rate determining step for ammonia synthesis.</p>


2019 ◽  
Author(s):  
Katsutoshi Sato ◽  
Shin-ichiro Miyahara ◽  
Yuta Ogura ◽  
Kotoko Tsujimaru ◽  
Yuichiro Wada ◽  
...  

<p>To mitigate global problems related to energy and global warming, it is helpful to develop an ammonia synthesis process using catalysts that are highly active under mild conditions. Here we show that the ammonia synthesis activity of Ru/Ba/LaCeO<i><sub>x</sub></i> pre-reduced at 700 °C is the highest reported among oxide-supported Ru catalysts. Our results indicate that low crystalline oxygen-deficient composite oxides, which include Ba<sup>2+</sup>, Ce<sup>3+</sup> and La<sup>3+</sup>, with strong electron-donating ability, accumulate on Ru particles and thus promote N≡N bond cleavage, which is the rate determining step for ammonia synthesis.</p>


2014 ◽  
Vol 3 (2) ◽  
pp. 22-26
Author(s):  
V. S. Prabhu ◽  
◽  
V. P. Surya Surendran ◽  
V. G. Veena ◽  
◽  
...  

2018 ◽  
Vol 9 (1) ◽  
pp. 7
Author(s):  
MOIN SIDDIQUI KHADIM ◽  
FATMA AMREEN ◽  
KHURSHEED SIDDIQUI MOHD ◽  
◽  
◽  
...  

2014 ◽  
pp. 298-301 ◽  
Author(s):  
Arnaud Petit

Bois-Rouge factory, an 8000 t/d cane Reunionese sugarcane mill, has fully equipped its filtration station with vacuum belt press filters since 2010, the first one being installed in 2009. The present study deals with this 3-year experience and discusses operating conditions, electricity consumption, performance and optimisation. The comparison with the more classical rotary drum vacuum filter station of Le Gol sugar mill highlights advantages of vacuum belt press filters: high filtration efficiency, low filter cake mass and sucrose content, low total solids content in filtrate and low power consumption. However, this technology needs a mud conditioning step and requires a large amount of water to improve mud quality, mixing of flocculant and washing of filter belts. The impact on the energy balance of the sugar mill is significant. At Bois-Rouge mill, studies are underway to reduce the water consumption by recycling low d.s. filtrate and by dry cleaning the filter belts.


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