Mechanochemical processes with the reaction-induced mechanical activation. Chemo-mechanochemical effect

2018 ◽  
Vol 67 (6) ◽  
pp. 933-948 ◽  
Author(s):  
V. V. Boldyrev
2013 ◽  
Vol 334-335 ◽  
pp. 369-374
Author(s):  
G.A. Kozhina ◽  
A.N. Ermakov ◽  
V.B. Fetisov ◽  
A.V. Fetisov ◽  
K. Y. Shunyaev ◽  
...  

Electrochemical behaviour of mechanoactivated β-MnO2 powders has been studied by the method of cyclic voltammetry with a carbon-paste electroactive electrode. Mechanical activation was carried out by dry grinding in an AGO-2 planetary ball mill. It was found that the grinding process results in a mechanochemical effect in the surface layer of the oxide particles: Mn (IV) cations are reduced to Mn (III). Voltammetry test detects that mechanical activation of β-MnO2 leads to a new state, which is characteristic for the γ-modification of manganese dioxide (β-MnO2 γ-MnO2).


In many rice producing countries of the world, including in Vietnam, various research aimed at using rice husk ash (RHA) as a finely dispersed active mineral additive in cements, concrete and mortars are being conducted. The effect of the duration of the mechanoactivation of the RHA, produced under laboratory conditions in Vietnam, on its pozzolanic activity were investigated in this study. The composition of ash was investigated by laser granulometry and the values of indicators characterizing the dispersion of its particles before and after mechanical activation were established. The content of soluble amorphous silicon oxide in rice husk ash samples was determined by photocolorimetric analysis. The pizzolanic activity of the RHA, fly ash and the silica fume was also compared according to the method of absorption of the solution of the active mineral additive. It is established that the duration of the mechanical activation of rice husk ash by grinding in a vibratory mill is optimal for increasing its pozzolanic activity, since it simultaneously results in the production of the most dispersed ash particles with the highest specific surface area and maximum solubility of the amorphous silica contained in it. Longer grinding does not lead to further reduction in the size of ash particles, which can be explained by their aggregation, and also reduces the solubility of amorphous silica in an aqueous alkaline medium.


2020 ◽  
Vol 94 (5) ◽  
pp. 1007-1010
Author(s):  
P. A. Konik ◽  
E. A. Berdonosova ◽  
E. V. Meshcheryakova ◽  
S. N. Klyamkin

ChemTexts ◽  
2021 ◽  
Vol 7 (2) ◽  
Author(s):  
Gudrun Scholz

Abstract This lecture text is focused on the comparatively young field of mechanochemistry of fluoride solids, considering both their mechanical activation and their mechanochemical synthesis. Beside a literature survey, the mechanochemical synthesis of binary fluorides MF2, MF3, of complex fluorides MMgF4, of solid solutions MaxMb1−xF2 or M1−xLnxF2+x (Ln: Y, Eu) and of fluorine-containing coordination polymers is presented. Owing to their interesting potential applications in the field of fluoride ion conductivity or luminescence properties when doped, most of the given examples are alkaline earth metal compounds. A short historical survey, remarks on peculiarities and consequences of mechanical activation as well as the necessary technical equipment for mechanochemical reactions precede the section. Graphic abstract


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