Hydrothermal synthesis, crystal structure, and photoluminescence of novel lanthanide metal organic frameworks constructed from 1,4-benzene-dicarboxylic acid and 1,2,4,5-benzenetetracarboxylic acid as ligands

2011 ◽  
Vol 23 (1) ◽  
pp. 275-285 ◽  
Author(s):  
Jian-Ling Wang ◽  
Ke-Ling Hou ◽  
Feng-Ying Bai ◽  
Yong-Heng Xing ◽  
Zhan Shi
Keyword(s):  
Crystal Structure ◽  
Hydrothermal Synthesis ◽  
Dicarboxylic Acid ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Benzene Dicarboxylic Acid

Two dimethylphenyl imidazole dicarboxylate-based lanthanide metal–organic frameworks for luminescence sensing of benzaldehyde

2015 ◽  
Vol 44 (9) ◽  
pp. 4362-4369 ◽  
Author(s):  
Bingbing Shi ◽  
Yuanhao Zhong ◽  
Lili Guo ◽  
Gang Li
Keyword(s):  
Dicarboxylic Acid ◽  
Metal Organic Frameworks ◽  
Hydrothermal Conditions ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Imidazole Dicarboxylate

Two novel dimethylphenyl imidazole dicarboxylate-based lanthanide(iii)-organic frameworks, [Ln(H2DMPhIDC)3(H3DMPhIDC)]n (Ln = Eu (1), Tb (2); H3DMPhIDC = 2-(3,4-dimethylphenyl)-1H-imidazole-4,5-dicarboxylic acid) have been synthesized under hydrothermal conditions.

scholarly journals Crystal Structure Dependence of the Energy Transfer from Tb(III) to Yb(III) in Metal–Organic Frameworks Based in Bispyrazolylpyridines

Crystals ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 69 ◽  
Author(s):  
Paloma Martinez-Martin ◽  
Josefina Perles ◽  
Juan Carlos Rodriguez-Ubis
Keyword(s):  
Crystal Structure ◽  
Energy Transfer ◽  
Organic Molecules ◽  
Metal Organic Frameworks ◽  
Structure Dependence ◽  
Characteristic Emission ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Coordinated Water ◽  
Luminescent Behavior

Luminescent mixed lanthanide metal−organic framwork (MOF) materials have been prepared from two polyheterocyclic diacid ligands, 2,6-bis(3-carboxy-1-pyrazolyl)pyridine and 2,6-bis(4-carboxy-1-pyrazolyl)pyridine. The crystal structures of the two organic molecules are presented together with the structures for the MOFs obtained by hydrothermal synthesis either with Yb(III) or mixed Tb(III)/Yb(III) ions. Different coordination architectures result from each ligand, revealing also important differences between the lanthanides. The mixed lanthanide metal−organic frameworks also present diverse luminescent behavior; in the case of 2,6-bis(4-carboxy-1-pyrazolyl)pyridine, where no coordinated water is present in the metal environment, Tb(III) and Yb(III) characteristic emission is observed by excitation of the bispyrazolylpyridine chromophore.

Assembly of porous lanthanide metal–organic frameworks constructed by chalcone dicarboxylic acid and exploration of their properties

Polyhedron ◽  
2019 ◽  
Vol 169 ◽  
pp. 24-31 ◽  
Author(s):  
Wei Pan ◽  
Chunhua Gong ◽  
Xianghua Zeng ◽  
Chenyan Hu ◽  
Yi Zhang ◽  
...  
Keyword(s):  
Dicarboxylic Acid ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Lanthanide Metal

scholarly journals Metal–organic frameworks constructed from crown ether-based 1,4-benzenedicarboxylic acid derivatives

2016 ◽  
Vol 45 (7) ◽  
pp. 3063-3069 ◽  
Author(s):  
Teng-Hao Chen ◽  
Andreas Schneemann ◽  
Roland A. Fischer ◽  
Seth M. Cohen
Keyword(s):  
Crown Ether ◽  
Dicarboxylic Acid ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Thiacrown Ether ◽  
Benzenedicarboxylic Acid ◽  
Metal Organic ◽  
Benzene Dicarboxylic Acid ◽  
Organic Framework

A series of crown ether- and thiacrown ether-derivatized benzene dicarboxylic acid (H2bdc) ligands has been synthesized and incorporated into the prototypical isoreticular metal–organic framework (IRMOF) and UiO-66 materials.

Two lanthanide metal–organic frameworks as sensitive luminescent sensors for the detection of Cr2+ and Cr2O72− in aqueous solutions

CrystEngComm ◽  
2018 ◽  
Vol 20 (2) ◽  
pp. 189-197 ◽  
Author(s):  
X. H. Huang ◽  
L. Shi ◽  
S. M. Ying ◽  
G. Y. Yan ◽  
L. H. Liu ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Dicarboxylic Acid ◽  
Metal Organic Frameworks ◽  
Hydrothermal Conditions ◽  
Luminescent Sensors ◽  
Benzenedicarboxylic Acid ◽  
Metal Organic ◽  
Lanthanide Metal

Two lanthanide–organic frameworks [Ln(HPIDC)(m-bdc)·1.5H2O]n (Ln = Eu 1 or Tb 2; H3PIDC = 2-(4-pyridyl)-1H-imidazole-4,5-dicarboxylic acid; m-H2bdc = 1,3-benzenedicarboxylic acid) were synthesized under hydrothermal conditions.

scholarly journals The effect of substituted benzene dicarboxylic acid linkers on the optical band gap energy and magnetic coupling in manganese trimer metal organic frameworks

2017 ◽  
Vol 5 (3) ◽  
pp. 539-548 ◽  
Author(s):  
K. S. Asha ◽  
Arthur C. Reber ◽  
N. Ahmed ◽  
R. Nath ◽  
Shiv N. Khanna ◽  
...  
Keyword(s):  
Dicarboxylic Acid ◽  
Band Gap ◽  
Optical Band Gap ◽  
Metal Organic Frameworks ◽  
Magnetic Coupling ◽  
Band Gap Energy ◽  
Gap Energy ◽  
Metal Organic ◽  
Benzene Dicarboxylic Acid

The optical band gap energy and magnetism of a series of Mn based compounds were tuned through linker modification.

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