Effect of CaF2 on the Reduction Swelling Properties of Iron Ore Briquettes in Different Reduction Stages

Author(s):  
Guocheng Zhang ◽  
Guoping Luo ◽  
Chenchen Sun
2021 ◽  
Vol 40 (1) ◽  
pp. 193-203
Author(s):  
Guo-Cheng Zhang ◽  
Guo-Ping Luo ◽  
Peng-Fei Jia ◽  
Yi-Ci Wang ◽  
Yi-Fan Chai

Abstract The influence mechanism of basicity on the reduction swelling index (RSI) of iron ore briquettes was investigated using the SEM analysis and Factsage 7.3 thermodynamic calculations based on the addition of pure CaO to Bayan Obo iron concentrate. The results revealed that the solid solution of Ca2+ in the FeO lattice increased with the basicity of the briquettes, whereas the diffusion channels of Fe2+ ions increased during the reduction process from FeO to Fe and resulted in the formation of a great number of slender and anisotropic iron whiskers, which consequently increased the RSI. Furthermore, the melting point of the slag phase decreased as the CaO content increased; this reduced its ability to resist the reduction swelling of iron oxides. When the basicity was increased from 0.3 to 0.8, the RSI reached a maximum of 69.85%. However, due to the saturated solid solution of Ca2+ in FeO lattice, as the basicity further increased from 0.8 to 1.2, excess CaO melting into the slag phase promoted the precipitation of spinel minerals with high melting points and difficult reduction properties. Thus, the diffusion of Fe2+ and the growth of the iron whiskers were hindered, and the RSI was reduced.


2021 ◽  
pp. 1-11
Author(s):  
Yingjie Fan ◽  
Yunhao Zhang ◽  
Zhichao Li ◽  
Yifan Chai ◽  
Yici Wang ◽  
...  

Author(s):  
Yufeng Guo ◽  
Kuo Liu ◽  
Feng Chen ◽  
Shuai Wang ◽  
Fuqiang Zheng ◽  
...  

2012 ◽  
Vol 52 (7) ◽  
pp. 1257-1265 ◽  
Author(s):  
Mikko Iljana ◽  
Olli Mattila ◽  
Tuomas Alatarvas ◽  
Ville-Valtteri Visuri ◽  
Jari Kurikkala ◽  
...  

2019 ◽  
Vol 55 (2) ◽  
pp. 167-175 ◽  
Author(s):  
T.-J. Chun ◽  
G.-T. Mu ◽  
Q.-M. Meng ◽  
H.-M. Long ◽  
P. Wang ◽  
...  

The preparation of MgO bearing iron ore pellets in the mini and pilot scales, and the application for 4070m3 blast furnace were conducted in this paper. The results show that with increasing the MgO content, the compressive strength of fired pellets decreased significantly, while the metallurgical performances, such as RI (reducibility index), RDI (reduction degradation index) and RSI (reduction swelling index) were improved. The scanning electron microscope with energy dispersive spectrometry was used to test the microstructures and the compositions of iron oxide, and the slag of pellets. With increasing the MgO content, MgO exists in the form of magnesium ferrite and monticellite, which presents the high melting temperature, decreasing the content of liquid phase. The pilot scale experiment was performed on a commercial running grate-rotary kiln with the annual output of 2.4 million tons of pellets, which agrees with the results obtained in the mini scale experiment. The application of MgO-bearing pellets was carried out in the 4070 m3 blast furnace of Meisteel China, and the production indexes improved with increasing the yield and reducing the coke ratio, and the total benefits are 7067 USD/d, which presents the superior economic benefits.


2013 ◽  
Vol 20 (10) ◽  
pp. 2806-2810 ◽  
Author(s):  
Bin Xu ◽  
Tong Hou ◽  
Xu-ling Chen ◽  
Qian Li ◽  
Tao Jiang ◽  
...  

2013 ◽  
Vol 53 (3) ◽  
pp. 419-426 ◽  
Author(s):  
Mikko Iljana ◽  
Olli Mattila ◽  
Tuomas Alatarvas ◽  
Jari Kurikkala ◽  
Timo Paananen ◽  
...  

1998 ◽  
Vol 37 (5) ◽  
pp. 441-448 ◽  
Author(s):  
Ramiro Conceição Nascimento ◽  
Marcelo Breda Movrão ◽  
José Deodoro Trani Capocchi

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