The ritter reaction of poly(acrylonitrile) with tert.-butyl alcohol

1980 ◽  
Vol 16 (11) ◽  
pp. 1075-1078
Author(s):  
V. Janout ◽  
P. Čefelín
Keyword(s):  
Butyl Alcohol ◽  
Ritter Reaction ◽  
Tert Butyl ◽  
Tert Butyl Alcohol ◽  
The Ritter Reaction ◽  
Poly Acrylonitrile

The Ritter reaction of the acrylonitrile oligomer

1980 ◽  
Vol 45 (7) ◽  
pp. 1928-1936 ◽  
Author(s):  
Václav Janout ◽  
Pavel Čefelín
Keyword(s):  
Functional Group ◽  
Conformational Equilibrium ◽  
Activation Enthalpy ◽  
Butyl Alcohol ◽  
Ritter Reaction ◽  
Activation Entropy ◽  
Tert Butyl Alcohol ◽  
Entropy Parameter ◽  
The Ritter Reaction ◽  
Poly Acrylonitrile

The Ritter reaction of oligomeric models of poly(acrylonitrile) with tert-butyl alcohol in tetramethylene sulphone leads to the respective N-tert-butylamides and proceeds via the second-order kinetics. The rate constants increase only little on passing from the monomeric to the trimeric model. The decrease in the activation enthalpy ΔH is almost compensated for by the decrease in the activation entropy parameter. No effect of the neighbouring functional group on the reaction kinetics could be observed. A new conformational equilibrium is established during the reaction.

Thermodynamic and Kinetic Investigation of the Solvent Effect on the Oxidation of [Co(en)2SCH2COO]+ with S2O82- In Water-Methanol and Water-tert-Butyl Alcohol Mixtures

1993 ◽  
Vol 58 (5) ◽  
pp. 1001-1006 ◽  
Author(s):  
Oľga Vollárová ◽  
Ján Benko
Keyword(s):  
Transfer Functions ◽  
Activation Parameters ◽  
Butyl Alcohol ◽  
Oxidation Of Co ◽  
Kinetics Of Oxidation ◽  
Tert Butyl ◽  
Tert Butyl Alcohol ◽  
Alcohol Mixtures ◽  
Kinetics Of

The kinetics of oxidation of [Co(en)2SCH2COO]+ with S2O82- was studied in water-methanol and water-tert-butyl alcohol mixtures. Changes in the reaction activation parameters ∆H≠ and ∆S≠ with varying concentration of the co-solvent depend on the kind of the latter, which points to a significant role of salvation effects. The solvation effect on the reaction is discussed based on a comparison of the transfer functions ∆Ht0, ∆St0 and ∆Gt0 for the initial and transition states with the changes in the activation parameters accompanying changes in the CO-solvent concentration. The transfer enthalpies of the reactant were obtained from calorimetric measurements.

scholarly journals Impacts of Sn(II) doping on the Keggin heteropolyacid-catalyzed etherification of glycerol with tert-butyl alcohol

2021 ◽  
pp. 116913
Author(s):  
Márcio José da Silva ◽  
Diego Morais Chaves ◽  
Sukarno Olavo ferreira ◽  
Rene Chagas da Silva ◽  
Jose Balena Gabriel Filho ◽  
...  
Keyword(s):  
Butyl Alcohol ◽  
Tert Butyl ◽  
Tert Butyl Alcohol

Selective alkylation of naphthalene with tert-butyl alcohol over HY zeolites modified with acid and alkali

2008 ◽  
Vol 9 (10) ◽  
pp. 1982-1986 ◽  
Author(s):  
Yingli Wang ◽  
Lei Xu ◽  
Zhengxi Yu ◽  
Xinzhi Zhang ◽  
Zhongmin Liu
Keyword(s):  
Butyl Alcohol ◽  
Tert Butyl ◽  
Tert Butyl Alcohol ◽  
Selective Alkylation ◽  
Hy Zeolites
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