Determination of the magnetite-water equilibrium oxygen isotope fractionation factor at 350°C: A comparison of ion microprobe and laser fluorination techniques

1995 ◽  
Vol 59 (18) ◽  
pp. 3871-3875 ◽  
Author(s):  
Steven M. Fortier ◽  
David R. Cole ◽  
David J. Wesolowski ◽  
Lee R. Riciputi ◽  
Bruce A. Paterson ◽  
...  
2019 ◽  
Vol 60 (11) ◽  
pp. 2101-2129 ◽  
Author(s):  
Alice Vho ◽  
Pierre Lanari ◽  
Daniela Rubatto

Abstract The knowledge of the fractionation behaviour between phases in isotopic equilibrium and its evolution with temperature is fundamental to assist the petrological interpretation of measured oxygen isotope compositions. We report a comprehensive and updated internally consistent database for oxygen isotope fractionation. Internal consistency is of particular importance for applications of oxygen isotope fractionation that consider mineral assemblages rather than individual mineral couples. The database DBOxygen is constructed from a large dataset of published experimental, semi-empirical and natural data, which were weighted according to type. It includes fractionation factors for 153 major and accessory mineral phases and a pure H2O fluid phase in the temperature range of 0–900°C, with application recommended for temperatures of 200–900°C. Multiple primary data for each mineral couple were discretized and fitted to a model fractionation function. Consistency between the models for each mineral couple was achieved by simultaneous least square regression. Minimum absolute uncertainties based on the spread of the available data were calculated for each fractionation factor using a Monte Carlo sampling technique. The accuracy of the derived database is assessed by comparisons with previous oxygen isotope fractionation calculations based on selected mineral/mineral couples. This database provides an updated internally consistent tool for geochemical modelling based on a large set of primary data and including uncertainties. For an effective use of the database for thermometry and uncertainty calculation we provide a MATLAB©-based software ThermoOx. The new database supports isotopic modelling in a thermodynamic framework to predict the evolution of δ18O in minerals during metamorphism.


2020 ◽  
Author(s):  
Madeleine Vickers ◽  
Stefano Bernasconi ◽  
Clemens Ullmann ◽  
Stephen Hesselbo ◽  
Gregory Price ◽  
...  

<p>Belemnite calcite has been used extensively for Jurassic and Cretaceous stable oxygen isotope temperature reconstructions since the 1950s. However, with the advent of clumped isotope thermometry, a consistent offset between reconstructed δ<sup>18</sup>O temperatures vs Δ<sub>47</sub> temperatures from the same belemnites has been observed. We investigate the causes of this offset by analyzing samples from the aragonitic phragmacone and calcitic rostrum from the same Cylindroteuthis belemnites, along with other aragonitic benthos, from the Callovian-aged Christian Malford Lagerstätte, U.K. Our new clumped isotope data suggest that the water-calcite <sup>18</sup>O-fractionation factor in belemnite calcite was larger than that of the commonly used δ<sup>18</sup>O thermometry equations (e.g. Kim and O’Neil, 1997), and which is currently observed in other marine calcifiers. Our reconstructions suggest that the oxygen isotope fractionation is compatible with that observed in slow-forming abiotic calcites (e.g. Coplen, 2007) and in rapidly precipitating Travertines (Kele et al. 2015). The application of more established δ<sup>18</sup>O thermometry equations (Kim and O’Neil, 1997) to belemnite calcite for temperature reconstructions has resulted in a consistent underestimation of belemnite calcification temperatures, which has led to erroneous conclusions about belemnite life habits, and underestimation of global temperatures during these greenhouse times. We therefore advocate the use of calcite equations based on low precipitation rate experiments (e.g. Coplen, 2007; Kele et al., 2015) for belemnite rostra temperature reconstructions.</p>


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