A simple formula for multicomponent gaseous diffusion coefficients derived from mean free path theory

1977 ◽  
Vol 20 (12) ◽  
pp. 1301-1306 ◽  
Author(s):  
E. Obermeier ◽  
A. Schaber
Keyword(s):  
Free Path ◽  
Diffusion Coefficients ◽  
Simple Formula ◽  
Mean Free Path ◽  
Gaseous Diffusion

Cation mobilities in liquid and supercritical C1–C4 hydrocarbons

1980 ◽  
Vol 58 (14) ◽  
pp. 1490-1494 ◽  
Author(s):  
Norman Gee ◽  
Gordon R. Freeman
Keyword(s):  
Free Path ◽  
Ion Mobility ◽  
Diffusion Coefficients ◽  
Critical Region ◽  
Mean Free Path ◽  
Liquid Viscosity ◽  
Boiling Points ◽  
Rough Approximation ◽  
The Relationship ◽  
Lower Liquid

The relationship between ion mobility and liquid viscosity is commonly expressed as μ [Formula: see text] η−m. In hydrocarbons the value of m tends to be near 1.0 at η > 5 mP, m > 1.0 at ~5 < η < 1 mP, and m < 1.0 at η < 0.5 mP. Thus there is a maximum in a plot of μη against η−1 and Walden's rule (m = 1.0) is only a rough approximation. The decrease of μη as the critical region is approached is accompanied by an increase in the ratio of diffusion coefficients Dmolec/Dion. Ion mobilities in the liquids well below their normal boiling points are chiefly controlled by the fluidity. At higher temperatures and concomitant lower liquid densities and viscosities μη first increases, due to an increasing ion mean free path, then decreases as the critical region is approached, due to the increasing liquid compressibility and consequent electrostriction about the ion.

scholarly journals Anisotropic Diffusion in Electron Swarms

1975 ◽  
Vol 28 (5) ◽  
pp. 533 ◽  
Author(s):  
JLA Francey ◽  
DA Jones
Keyword(s):  
Free Path ◽  
Diffusion Coefficients ◽  
Anisotropic Diffusion ◽  
Collision Frequency ◽  
Mean Free Path ◽  
Distribution Functions ◽  
Isotropic Diffusion ◽  
Electrostatic Fields ◽  
Frequency Interaction

We show that the distribution functions derived by Parker (1963) in his analysis of the TownsendHuxley experiment can be used to calculate DL/D, the ratio of longitudinal to isotropic diffusion coefficients for electron swarms in electrostatic fields in gases. In the case of a constant collision frequency interaction our results agree with previous calculations, whilst for a constant mean free path we find DL/D = 0�58. This result is some 16% higher than previously published values but provides better agreement with experiment for electrons in helium.

Inelastic mean free path and phase-shift determinations in NiO, using EXELFS

1993 ◽  
Vol 3 (7) ◽  
pp. 1649-1659
Author(s):  
Mohammad A. Tafreshi ◽  
Stefan Csillag ◽  
Zou Wei Yuan ◽  
Christian Bohm ◽  
Elisabeth Lefèvre ◽  
...  
Keyword(s):  
Phase Shift ◽  
Free Path ◽  
Mean Free Path ◽  
Inelastic Mean Free Path

The measurement of mean free path λs using a slowing down time lead spectrometer in the 1–10 eV energy region

1968 ◽  
Vol 22 (4) ◽  
pp. 261-262
Author(s):  
M.P. Navalkar ◽  
K. Chandramoleshwar ◽  
D.V.S. Ramkrishna
Keyword(s):  
Free Path ◽  
Energy Region ◽  
Mean Free Path ◽  
Slowing Down ◽  
Time Lead

scholarly journals Controllable transport mean free path of light in xerogel matrixes embedded with polystyrene spheres

2009 ◽  
Vol 17 (9) ◽  
pp. 6975 ◽  
Author(s):  
Boris P. Bret ◽  
Nuno J. Couto ◽  
Mariana Amaro ◽  
Eduardo J. Nunes-Pereira ◽  
Michael Belsley
Keyword(s):  
Free Path ◽  
Mean Free Path ◽  
Polystyrene Spheres

An experimental method for calibration of the plasmon mean free path

2009 ◽  
Vol 236 (3) ◽  
pp. 165-173 ◽  
Author(s):  
H. MELTZMAN ◽  
Y. KAUFFMANN ◽  
P. THANGADURAI ◽  
M. DROZDOV ◽  
M. BARAM ◽  
...  
Keyword(s):  
Experimental Method ◽  
Free Path ◽  
Mean Free Path
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