Palladium(II) complex formation by indole-3-acetate. Mixed ligand complexes involving a unique spiro-ring formed by cyclopalladation

1995 ◽  
Vol 235 (1-2) ◽  
pp. 367-374 ◽  
Author(s):  
Masako Takani ◽  
Hideki Masuda ◽  
Osamu Yamauchi
2015 ◽  
Vol 11 (4) ◽  
pp. 3488-3498
Author(s):  
Kerim A. Kuliyev

Mixed-ligand complexes of Vanadium (IV, V) with 2,6-dithiol-4-methylphenol (DTMP) and hydrofobamins(Am) have been studied by spectrophotometry. Extraction of mixed ligand complexes is maximal at pH 3.8-5.3. The optimal conditions for the formation and extraction of mixed-ligand compounds have been found and the ratios of components I the complexes have been determined. The Beer’s law was applicable in the range of 0.04-3.6mg/ml.The method is free from common interferences. A procedure has been developed for extraction – spectro-photometric determination vanadium in soils andin oil and oil-products.


2021 ◽  
Vol 1 (1) ◽  
Author(s):  
Kumari Seema ◽  
◽  
Rajneesh Kumar ◽  

The present investigation has been undertaken to examine complex formation by thallium (I) derivatives of 2-nitro phenol (ONP), 2,4-dinitrophenol (DNP), 2,4,6-trinitrophenol (TNP), 1-nitroso-2-naphthol (1N2N), 8-hydroxyquinoline (8HQ), and 2-aminobenzoic acid (OABA) with Isonitrosoethylmethyl Ketone. They have general formula [ML (HL′)], where M = Tl (I), L = deprotonated ONP, DNP, TNP, 8-HQ, 1N2N and OABA and L′ = Isonitrosoethylmethyl Ketone. Isonitrosoethylmethyl Ketone is ambidentate ligand and can donate through oxygen or nitrogen or both. The preparation of mixed ligand complex with the thallium (I) salt of 2,4-dinitrophenol and 2,4,6-trinitrophenol with the Isonitrosoethylmethyl Ketone (INEMK) have very low yield.


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