Temperature dependence of hydroxylic proton hyperfine coupling constant in complexes of nitroxide radical with alcohols

1977 ◽  
Vol 28 (1) ◽  
pp. 63-67
Author(s):  
W Kolodziejski ◽  
Z Kȩcki
Keyword(s):  
Temperature Dependence ◽  
Hyperfine Coupling ◽  
Nitroxide Radical ◽  
Hyperfine Coupling Constant ◽  
Coupling Constant ◽  
Hydroxylic Proton

The β-phosphorus hyperfine coupling constant in nitroxides: 6. Solvent effects in non-cyclic nitroxides

2016 ◽  
Vol 14 (15) ◽  
pp. 3729-3743 ◽  
Author(s):  
Gérard Audran ◽  
Lionel Bosco ◽  
Paulin Nkolo ◽  
Raphael Bikanga ◽  
Paul Brémond ◽  
...  
Keyword(s):  
Solvent Effects ◽  
Hyperfine Coupling ◽  
Hyperfine Coupling Constant ◽  
Coupling Constant ◽  
The Impact

The impact of the solvent on aP and aN decreases strikingly upon increasing both the bulkiness and the polarity of the substituents around the nitroxyl moiety.

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