The reactivity of the metalmetal bond in the dimer [(CH3C(CH2PPh2)3)2Rh2(μ-CO)2]·(CH3)2CO. Synthesis and X-ray structure of a paramagnetic dinuclear rhodium complex

1988 ◽  
Vol 353 (1) ◽  
pp. C5-C9 ◽  
Author(s):  
Franco Cecconi ◽  
Carlo A. Ghilardi ◽  
Stefano Midollini ◽  
Annabella Orlandini ◽  
Piero Zanello ◽  
...  
Keyword(s):  
X Ray ◽  
1993 ◽  
Vol 12 (8) ◽  
pp. 2888-2890 ◽  
Author(s):  
Daniel Miguel ◽  
Julio A. Perez-Martinez ◽  
Victor Riera ◽  
Santiago Garcia-Granda

2003 ◽  
Vol 07 (02) ◽  
pp. 120-124 ◽  
Author(s):  
Jean-Michel Barbe ◽  
Gérald Morata ◽  
Enrique Espinosa ◽  
Roger Guilard

The nucleophilic attack of a rhodium(I) porphyrin on a chlorotin(IV) corrole yields the heterobinuclear rhodium porphyrin-tin corrole complex where the two metals are bound via a single metal-metal bond. The X-ray structure of the rhodium tetraphenylporphyrin-tin(2,3,7,13,17,18-hexamethyl-8,12-diethylcorrole) complex is reported. The Rh-Sn single bond distance is equal to 2.5069(7) Å and the Rh and Sn atoms are located at 0.076 and 0.793 Å from the porphyrin and the corrole 4N mean planes, respectively.


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