Chain transfer reactions in the anionic polymerization of octamethylcyclotetrasiloxane

1962 ◽  
Vol 3 (3) ◽  
pp. 514-525 ◽  
Author(s):  
M. Kučera ◽  
M. Jelinek
Keyword(s):  
Anionic Polymerization ◽  
Chain Transfer ◽  
Transfer Reactions

The kinetics of chain transfer in anionic polymerization of propylene oxide

1973 ◽  
Vol 15 (6) ◽  
pp. 1370-1376 ◽  
Author(s):  
G.A. Gladkovskii ◽  
L.P. Golovina ◽  
G.F. Vedeneyeva ◽  
V.S. Lebedev
Keyword(s):  
Propylene Oxide ◽  
Anionic Polymerization ◽  
Chain Transfer ◽  
Kinetics Of

Incorporation of Antioxidant Groups into Polydienes. I. Via Chain Transfer Reactions of Symmetrical Dithiodiphenols

1977 ◽  
Vol 50 (4) ◽  
pp. 641-649 ◽  
Author(s):  
A. H. Weinstein
Keyword(s):  
Chain Transfer ◽  
Chain Transfer Agent ◽  
Transfer Reactions ◽  
Oxygen Absorption ◽  
Transfer Activity ◽  
Transfer Agents

Abstract A number of substituted symmetrical dithiodiphenols and related monothio-and trithiodiphenols were prepared and characterized. Some of these dithiodiphenols showed chain transfer activity either in bulk styrene or in emulsion diene polymerizations. The fact that phenolic sulfide units were incorporated into polyisoprene and polybutadiene by use of one of these compounds, 2,2′-dithiobis(6-t-butyl-p-cresol), as chain transfer agent was confirmed by ultraviolet analysis. It was demonstrated that selfresistance to oxidation was incorporated into various diene homo- or copolymers, to varying degree, by use of some of these dithiodiphenols as chain transfer agents, on the basis of oxygen absorption tests on preextracted polymers.

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