Magnetic properties of some rare earth monoxides LnO (Ln = Pr, Nd, Sm) mixed valence state of SmO

1980 ◽  
Vol 33 (3) ◽  
pp. 351-353 ◽  
Author(s):  
G. Krill ◽  
M.F. Ravet ◽  
J.P. Kappler ◽  
L. Abadli ◽  
J.M. Leger ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Rare Earth ◽  
Valence State ◽  
Mixed Valence ◽  
Mixed Valence State

The synthesis and magnetic properties of a linear mixed-valence [Ni3]5+ in an anthyridine tri-nickel complex

2019 ◽  
Vol 48 (27) ◽  
pp. 9912-9915
Author(s):  
Chang-Lin Hsieh ◽  
Tsai-Jung Liu ◽  
You Song ◽  
Gene-Hsiang Lee ◽  
Bih-Yaw Jin ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Valence State ◽  
Nickel Complex ◽  
Mixed Valence ◽  
Trinuclear Complex ◽  
Tridentate Ligand ◽  
Sodium Tetraphenylborate ◽  
Mixed Valence State

A novel trinuclear complex [Ni3(μ3-dbay)4Cl2]I3 (1) with a mixed-valence state was prepared by reacting the tridentate ligand 1,13,14-triaza-dibenz[a,j]anthracene (dibenzanthyridine = dbay) with anhydrous NiCl2 and sodium tetraphenylborate.

Synthesis, structure, and magnetic properties of the quaternary oxysulfides Ln 5V3O7S6 (Ln = La, Ce)

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Chong Zheng ◽  
Roald Hoffmann ◽  
Timothy S. Perkins ◽  
Frank Calvagna ◽  
Roxanna Fotovat ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Magnetic Susceptibility ◽  
Rare Earth ◽  
Valence State ◽  
Mixed Valence ◽  
Magnetic Behavior ◽  
Magnetic Susceptibility Measurement ◽  
Orthorhombic Space Group ◽  
One Dimensional ◽  
The Matrix

Abstract Two rare earth oxysulfides Ln 5V3O7S6 (Ln = La, Ce) have been synthesized and their structures determined. The two isostructural compounds crystallize in the orthorhombic space group Pmmn (no. 59). The structure features one-dimensional edge-sharing VS4O2 octahedron chains parallel to the b axis. The bonding between V and S/O is covalent, and between Ln 3+ and the rest of the matrix ionic. Magnetic susceptibility measurement revealed that V is in a mixed valence state of V3+ and V4+. Its magnetic behavior follows the Curie-Weiss law.

Theory for the mixed-valence state

1979 ◽  
Vol 40 (C5) ◽  
pp. C5-374-C5-374 ◽  
Author(s):  
C. M. Varma
Keyword(s):  
Valence State ◽  
Mixed Valence ◽  
Mixed Valence State

MIXED VALENCE STATE OF Sm ON THE SURFACE OF AMORPHOUS La80-xSmxAu20 ALLOYS

1980 ◽  
Vol 41 (C8) ◽  
pp. C8-799-C8-802 ◽  
Author(s):  
G. Krill ◽  
A. Amamou ◽  
A. Berrada ◽  
J. Durand ◽  
N. Hassanain
Keyword(s):  
Valence State ◽  
Mixed Valence ◽  
Mixed Valence State

scholarly journals Mixed-Valence State of Europium in the Misfit Layer Compound (EuS)1.173NbS2.

ChemInform ◽  
2003 ◽  
Vol 34 (20) ◽  
Author(s):  
Laurent Cario ◽  
Pierre Palvadeau ◽  
Alain Lafond ◽  
Catherine Deudon ◽  
Yves Moelo ◽  
...  
Keyword(s):  
Valence State ◽  
Mixed Valence ◽  
Layer Compound ◽  
Mixed Valence State

scholarly journals Investigation of Mixed Valence State of Sm_{1-x}B_{6} and Sm_{1-x}La_{x}B_{6} by XANES

2014 ◽  
Vol 126 (1) ◽  
pp. 338-339 ◽  
Author(s):  
S. Gabáni ◽  
K. Flachbart ◽  
J. Bednarčík ◽  
E. Welter ◽  
V. Filipov ◽  
...  
Keyword(s):  
Valence State ◽  
Mixed Valence ◽  
Mixed Valence State
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