Excess molar enthalpies, densities and excess molar volumes for binary mixtures containing dimethyl carbonate or diethyl carbonate + 2,2,4-trimethylpentane at 288.15, 298.15, and 313.5 K, and at atmospheric pressure. Application of an extended cell model

1996 ◽  
Vol 277 ◽  
pp. 121-132 ◽  
Author(s):  
Romolo Francesconi ◽  
Fabio Comelli ◽  
Stefano Ottani
2017 ◽  
Vol 232 (1) ◽  
Author(s):  
Wei Song ◽  
Hai Zhang ◽  
Zhenyu Yang ◽  
Juan Wang ◽  
Zishuang Yue ◽  
...  

AbstractIn this work, the experimental densities and viscosities have been determined for (propylene carbonate+acetonitrile, or dimethyl carbonate, or diethyl carbonate) binary mixtures over the whole concentration range at temperatures (293.15–333.15 K) and the atmospheric pressure. Excess molar volumes (


1995 ◽  
Vol 73 (1) ◽  
pp. 139-145 ◽  
Author(s):  
José M. Pico ◽  
Consolaciôn P. Menaut ◽  
Eulogio Jiménez ◽  
José L. Legido ◽  
Josefa Fernàndez ◽  
...  

Excess molar volumes υE at 298.15 and 308.15 K and normal atmospheric pressure for the binary mixtures 2-pentanone + 1-chloroalkane (from 1-chlorobutane to 1-chlorooctane) were obtained from measurements of the density with an Anton Paar densimeter. The υE values for all mixtures were positive, and increase as the 1-chloroalkane length increases. Excess molar volumes depend slightly on the temperature. The same characteristics were found previously for the excess molar enthalpies of the same mixtures. Experimental υE values are compared with theoretical results using the Prigogine–Flory–Patterson model. Keywords: thermodynamics, liquid mixtures, excess volumes, ketones, chloroalkanes.


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