Excess Molar Enthalpies and Excess Molar Volumes of Binary Mixtures Containing 1,3-Dioxolane or 1,4-Dioxane + Pine Resins at (298.15 and 313.15) K and at Atmospheric Pressure

2001 ◽  
Vol 46 (3) ◽  
pp. 577-581 ◽  
Author(s):  
Romolo Francesconi ◽  
Carlo Castellari ◽  
Fabio Comelli

1995 ◽  
Vol 73 (1) ◽  
pp. 139-145 ◽  
Author(s):  
José M. Pico ◽  
Consolaciôn P. Menaut ◽  
Eulogio Jiménez ◽  
José L. Legido ◽  
Josefa Fernàndez ◽  
...  

Excess molar volumes υE at 298.15 and 308.15 K and normal atmospheric pressure for the binary mixtures 2-pentanone + 1-chloroalkane (from 1-chlorobutane to 1-chlorooctane) were obtained from measurements of the density with an Anton Paar densimeter. The υE values for all mixtures were positive, and increase as the 1-chloroalkane length increases. Excess molar volumes depend slightly on the temperature. The same characteristics were found previously for the excess molar enthalpies of the same mixtures. Experimental υE values are compared with theoretical results using the Prigogine–Flory–Patterson model. Keywords: thermodynamics, liquid mixtures, excess volumes, ketones, chloroalkanes.





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