Photochemistry of the gaseous hydrogen peroxide—carbon monoxide system. II: Rate constants for hydroxyl radical reactions with hydrocarbons and for hydrogen atom reactions with hydrogen peroxide

1974 ◽  
Vol 3 (1) ◽  
pp. 115-122 ◽  
Author(s):  
R.A. Gorse ◽  
D.H. Volman
Keyword(s):  
Hydrogen Peroxide ◽  
Carbon Monoxide ◽  
Hydrogen Atom ◽  
Hydroxyl Radical ◽  
Rate Constants ◽  
Gaseous Hydrogen ◽  
Radical Reactions

Radiolysis studies on the corrosion inhibitors 1 -hexyn-3-ol, cinnamonitrile, and 1,3-diethyl-2-thiourea

1995 ◽  
Vol 73 (12) ◽  
pp. 2137-2142 ◽  
Author(s):  
A.J. Elliot ◽  
M.P. Chenier ◽  
D.C. Ouellette
Keyword(s):  
Hydrogen Atom ◽  
Hydroxyl Radical ◽  
Temperature Dependence ◽  
Rate Constant ◽  
Rate Constants ◽  
Corrosion Inhibitors ◽  
Hydrated Electron

In this publication we report: (i) the rate constants for reaction of the hydrated electron with 1-hexyn-3-ol ((8.6 ± 0.3) × 108 dm3 mol−1 s−1 at 18 °C), cinnamonitrile ((2.3 ± 0.2) × 1010 dm3 mol−1 s−1 at 20 °C), and 1,3-diethyl-2-thiourea ((3.5 ± 0.3) × 108 dm3 mol−1 s−1 at 22 °C). For cinnamonitrile and diethylthiourea, the temperature dependence up to 200 °C and 150 °C, respectively, is also reported; (ii) the rate constants for the reaction of the hydroxyl radical with 1-hexyn-3-ol ((5.5 ± 0.5) × 109 dm3 mol−1 s−1 at 20 °C), cinnamonitrile ((9.2 ± 0.3) × 109 dm3 mol−1 s−1 at 21 °C), and diethylthiourea ((8.0 ± 0.8) × 108 dm3 mol−1 s−1 at 22 °C). For cinnamonitrile, the temperature dependence up to 200 °C is also reported; (iii) the rate constant for the hydrogen atom reacting with 1-hexyn-3-ol ((4.3 ± 0.4) × 109 dm3 mol−1 s−1 at 20 °C). Keywords: radiolysis, corrosion inhibitors, rate constants.

scholarly journals Comparison of hydrogen atom and hydroxyl radical reactions with simple aromatic molecules in aqueous solution

2020 ◽  
Vol 534 ◽  
pp. 110754 ◽  
Author(s):  
Renáta Homlok ◽  
Viktória Mile ◽  
Erzsébet Takács ◽  
Gábor Járvás ◽  
Szabolcs Góger ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Hydrogen Atom ◽  
Hydroxyl Radical ◽  
Radical Reactions ◽  
Aromatic Molecules
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