Fundamentals of Maxwell's kinetic theory of a simple monatomic gas

1980 ◽  
Vol 7 (9) ◽  
pp. 527
Author(s):  
S. Simons
Keyword(s):  

In order to extend Maxwell's later method of developing the dynamical theory of a gas to cases other than that which he considered (viz., a gas whose molecules are point centres of repulsive force varying inversely as the fifth power of the distance), a knowledge of the velocity distribution function, in the disturbed state of the gas, is necessary. In this paper the simplest possible form is assumed for the function, consistent with the fulfilment of certain preliminary conditions. This form is ( hm / π ) 3/2 e - hm ∑( u - u 0 ) 2 {1 + F ( u - u 0 , v - v 0 , w - w 0 )}, where F is a polynomial, in the three variables indicated, of the third degree. The theory of viscosity and thermal conduction, in simple and mixed gases, is developed without assuming any property of the molecules beyond that of spherical symmetry. Perhaps the most interesting result is the relation between the viscosity μ , the thermal conductivity ϑ, and the specific heat at constant volume, C v , for a simple monatomic gas, viz., ϑ = 5/2 μ C v .


Author(s):  
Robert T. Hanlon

Rudolf Clausius developed the first modern version of the kinetic theory of gases. His derivation provided the means to predict the heat capacity of a monatomic gas and to quantify the mean free path distance traveled by atoms between collisions.


The present memoir was originally intended to deal only with the theory of diffusion, which still remains its chief subject. During the course of the work, however, it became clear that the theory of viscosity and thermal conduction could also be incorporated by a slight extension of the analysis. This has been done, and the paper now affords an account of all these three “ordinary” mean-free-path phenomena of a composite gas. The treatment of viscosity and conduction is brief, partly because the theory for a composite gas is so much more complex and less important than that for a simple gas. For the same reason the results are not carried to a higher degree of approximation than that attained, in regard to the same phenomena, in an earlier memoir. The present method, however, enables the approximation to be carried to any degree of accuracy, which was not formerly possible. Also a certain mistake in the previous investigation of the conductivity of a composite gas is indicated and corrected.


The kinetic theory of gases can be developed accurately only after the distribution of the molecular velocities has been determined. This was done by Maxwell in the case of a uniform gas, and by means of his well-known law of distribution the pressure and temperature can be precisely expressed in terms of the molecular data. His law does not suffice, however, for the investigation of diffusion, viscosity, or thermal conduction, since these occur only when the gas is not uniform in composition, mean velocity, or energy. An accurate theory of these phenomena must be based on the evaluation of the modified velocity-distribution function, a task which for many decades has constituted one of the classical unsolved problems of the kinetic theory. In one special case, as Maxwell found, the actual determination of this function proves to be unnecessary for the purpose mentioned; this is the case of a gas composed of molecules which are point centres of force varying inversely as the fifth power of the distance. The reasons for the peculiarity in this instance are analytical and not physical, and unfortunately for the simplicity of the mathematical theory of gases, Maxwell’s results for such a gas do not accord with the observed data of actual gases. This particular molecular model is therefore interesting chiefly on theoretical grounds, and it is important to develop the theory for molecules of other types, which may better represent the behaviour of real molecules.


Author(s):  
Gregory V. Vereshchagin ◽  
Alexey G. Aksenov

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