Microscopic theory of third-harmonic generation and electro-absorption in conjugated polymers

1992 ◽  
Vol 49 (1-3) ◽  
pp. 1-11 ◽  
Author(s):  
Dandan Guo ◽  
S. Mazumdar ◽  
S.N. Dixit
1996 ◽  
Vol 53 (8) ◽  
pp. 4367-4376 ◽  
Author(s):  
A. Mathy ◽  
K. Ueberhofen ◽  
R. Schenk ◽  
H. Gregorius ◽  
R. Garay ◽  
...  

1989 ◽  
Vol 173 ◽  
Author(s):  
R. Zamboni ◽  
C. Taliani ◽  
G. Ruani ◽  
A. J. Pal ◽  
F. Kajzar

ABSTRACTNonlinear optical properties of two thiophene-based conjugated polymers (PTT and PDTB) were studied by the photoinduced absorption spectroscopy and the third harmonic generation spectroscopy. The results obtained with these two methods are used to estimate the value of χ(3) in these materials. Resonant χ(3) are (2.0 ± 0.2) × 10−11 e.s.u. and (1.0 ± 0.1) × 10−11 e.s.u. for PTT and PDTB, respectively. χ(3) is shown to be related to the width of the optical gap through a sixth-power law. In PTT a vibronic structure due to the C = C stretching mode appears in the χ(3) spectrum.


Materials ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3194
Author(s):  
Adrian Petris ◽  
Petronela Gheorghe ◽  
Tudor Braniste ◽  
Ion Tiginyanu

The ultrafast third-order optical nonlinearity of c-plane GaN crystal, excited by ultrashort (fs) high-repetition-rate laser pulses at 1550 nm, wavelength important for optical communications, is investigated for the first time by optical third-harmonic generation in non-phase-matching conditions. As the thermo-optic effect that can arise in the sample by cumulative thermal effects induced by high-repetition-rate laser pulses cannot be responsible for the third-harmonic generation, the ultrafast nonlinear optical effect of solely electronic origin is the only one involved in this process. The third-order nonlinear optical susceptibility of GaN crystal responsible for the third-harmonic generation process, an important indicative parameter for the potential use of this material in ultrafast photonic functionalities, is determined.


2021 ◽  
Vol 1859 (1) ◽  
pp. 012050
Author(s):  
Z Kasapeteva ◽  
A Dakova ◽  
V Slavchev ◽  
D Dakova ◽  
L Kovachev ◽  
...  

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