Supported transition metal complexes for ethylene polymerization

1996 ◽  
Vol 107 (1-3) ◽  
pp. 113-121 ◽  
Author(s):  
Giuseppe Braca ◽  
Glauco Sbrana ◽  
Anna Maria Raspolli-Galletti ◽  
Angelina Altomare ◽  
Guillermo Arribas ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Ethylene Polymerization

scholarly journals The charge percolation mechanism and simulation of Ziegler-Natta polymerizations, part VI: Mechanism of ethylene polymerization by supported chromium oxide

2007 ◽  
Vol 72 (11) ◽  
pp. 1155-1169 ◽  
Author(s):  
Dragoslav Stoiljkovic ◽  
Branka Pilic ◽  
Misa Bulajic ◽  
Nebojsa Djurasovic ◽  
Nikolaj Ostrovski
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Chromium Oxide ◽  
Ethylene Polymerization ◽  
Olefin Polymerization ◽  
Intensive Research ◽  
A Charge

Despite intensive research over the last 50 years, many questions concerning ethylene polymerization by supported chromium oxide are still unanswered. Hence, the very fundamental issues of this polymerization are discussed in this paper. It is shown that a charge percolation mechanism (CPM) of olefin polymerization by Ziegler-Natta transition metal complexes, recently proposed by us, can give the answers in this case, too.

Syntheses of group 4 transition metal complexes bearing 2-pyridinethiolate ligands and their catalytic activities for ethylene polymerization

Polymer ◽  
2006 ◽  
Vol 47 (16) ◽  
pp. 5762-5774 ◽  
Author(s):  
Yoshinori Takashima ◽  
Yuushou Nakayama ◽  
Mika Hashiguchi ◽  
Takashi Hosoda ◽  
Hajime Yasuda ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Ethylene Polymerization ◽  
Catalytic Activities ◽  
Group 4
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