New Discrete Models and Their Application to Mechanics of Granular Materials

Author(s):  
T. KAWAI ◽  
N. TAKEUCHI
2019 ◽  
Vol 25 (2) ◽  
pp. 407-429 ◽  
Author(s):  
Nima Nejadsadeghi ◽  
Anil Misra

For many problems in science and engineering, it is necessary to describe the collective behavior of a very large number of grains. Complexity inherent in granular materials, whether due the variability of grain interactions or grain-scale morphological factors, requires modeling approaches that are both representative and tractable. In these cases, continuum modeling remains the most feasible approach; however, for such models to be representative, they must properly account for the granular nature of the material. The granular micromechanics approach has been shown to offer a way forward for linking the grain-scale behavior to the collective behavior of millions and billions of grains while keeping within the continuum framework. In this paper, an extended granular micromechanics approach is developed that leads to a micromorphic theory of degree n. This extended form aims at capturing the detailed grain-scale kinematics in disordered (mechanically or morphologically) granular media. To this end, additional continuum kinematic measures are introduced and related to the grain-pair relative motions. The need for enriched descriptions is justified through experimental measurements as well as results from simulations using discrete models. Stresses conjugate to the kinematic measures are then defined and related, through equivalence of deformation energy density, to forces conjugate to the measures of grain-pair relative motions. The kinetic energy density description for a continuum material point is also correspondingly enriched, and a variational approach is used to derive the governing equations of motion. By specifying a particular choice for degree n, abridged models of degrees 2 and 1 are derived, which are shown to further simplify to micro-polar or Cosserat-type and second-gradient models of granular materials.


Author(s):  
Marek Capinski ◽  
Ekkehard Kopp

1998 ◽  
Vol 77 (5) ◽  
pp. 1413-1425 ◽  
Author(s):  
Dietrich E.Wolf, Farhang Radjai, Sabine Dipp
Keyword(s):  

2020 ◽  
Vol 63 (6) ◽  
pp. 545-561
Author(s):  
V N Dolgunin ◽  
A N Kudi ◽  
M A Tuev

2013 ◽  
Vol 58 (1) ◽  
pp. 32-39
Author(s):  
O.I. Gerasymov ◽  
◽  
A.G. Zagorodny ◽  
M.M. Somov ◽  
◽  
...  
Keyword(s):  

Author(s):  
Shiwei Wang ◽  
Anton Chavez ◽  
Simil Thomas ◽  
Hong Li ◽  
Nathan C. Flanders ◽  
...  

This work reports on the assembly of imine-linked macrocycles that serve as models of two-dimensional covalent organic frameworks (2D COFs). Interlayer interactions play an important role in the formation of 2D COFs, yet the effect of monomer structure on COF formation, crystallinity, and susceptibility to exfoliation are not well understood. For example, monomers with both electron-rich and electron-poor π-electron systems have been proposed to strengthen interlayer inter-actions and improve crystallinity. Here we probe these effects by studying the stacking behavior of imine-linked macrocycles that represent discrete models of 2D COFs. <div><br></div><div>Specifically, macrocycles based on terephthaldehyde (PDA) or 2,5-dimethoxyterephthaldehyde (DMPDA) stack upon cooling molecularly dissolved solutions. Both macrocycles assemble cooperatively with similar ΔHe values of -97 kJ/mol and -101 kJ/mol, respectively, although the DMPDA macrocycle assembly process showed a more straightforward temperature dependence. Circular dichroism spectroscopy performed on macrocycles bearing chiral side chains revealed a helix reversion process for the PDA macrocycles that was not observed for the DMPDA macrocycles. <br></div><div><br></div><div>Given the structural similarity of these monomers, these findings demonstrate that the stacking processes associated with nanotubes derived from these macrocycles, as well as for the corresponding COFs, are complex and susceptible to kinetic traps, casting doubt on the relevance of thermodynamic arguments for improving materials quality. <br></div>


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