Cross-metathesis reactions of allyl chloride with fatty acid methyl esters: Efficient synthesis of α,ω-difunctional chemical intermediates from renewable raw materials

2009 ◽  
Vol 353 (1) ◽  
pp. 32-35 ◽  
Author(s):  
Tina Jacobs ◽  
Anastasiya Rybak ◽  
Michael A.R. Meier
2014 ◽  
Vol 117 (2) ◽  
pp. 209-216 ◽  
Author(s):  
Hélène Bonin ◽  
Adel Keraani ◽  
Jean-Luc Dubois ◽  
Markus Brandhorst ◽  
Cédric Fischmeister ◽  
...  

Transport ◽  
2012 ◽  
Vol 27 (2) ◽  
pp. 111-117 ◽  
Author(s):  
Eglė Sendžikienė ◽  
Violeta Makarevičienė ◽  
Svitlana Kalenska

Possible alternative raw materials for producing biodiesel fuel are as follows: Camelina sativa oil, fibre linseed oil and waste animal fat. The aim of this work was to analyse the emissions of the engine running on multi-component fuels containing fossil diesel fuel (D), linseed or Camelina sativa oil fatty acid methyl esters (LSME and CME respectively) and beef tallow (TME) fatty acid methyl esters. The concentration of fatty acid methyl esters (FAME) in the mixtures with fossil diesel fuel varied from 10% to 30%. The mass proportion of LSME (or CME) and TME in the mixtures was 1:4. The lowest NOxconcentration in exhaust gases was observed when the mixtures contained 10% of biofuel. For the mixtures containing CME and LSME, NOx concentrations reached 290 and 295 ppm respectively when the engine rotation speed was 1200 min−1 and 370 and 375 ppm respectively when rotation speed was 2000 min−1. CO concentration was the lowest when fuel contained 30% of the FAME mixture. HC concentration was slightly higher when the mixtures containing LSME were used relative to the mixtures containing CME. The amount of HC did not fluctuate considerably (195÷254 ppm) at rotation speeds between 1200 and 2000 min−1. Lower HC concentration was found in exhaust gas when the fuels containing 10% and 20% of biofuel were used. The lowest concentration of polycyclic aromatic hydrocarbons (PAHs) was found when the mixtures contained 30% of biofuel made of LSME or CME corresponding to 30 µg/m3 and 38 µg/m3 at a rotation speed of 1200 min−1 and 640 µg/m3 and 670 µg/m3 at a rotation speed of 2000 min−1 respectively. The greatest amount of smokiness at a high rotation speed of 2000 min−1 was observed when the mixture contained 30% of multi-component biodiesel fuel. It was found that the fuel containing a mixture of 30% of LSME biofuel and 20% of CME biofuel had a small advantage.


ACS Omega ◽  
2018 ◽  
Vol 3 (9) ◽  
pp. 11041-11049 ◽  
Author(s):  
Duy Le ◽  
Chanatip Samart ◽  
Ken Tsutsumi ◽  
Kotohiro Nomura ◽  
Suwadee Kongparakul

2011 ◽  
Vol 347-353 ◽  
pp. 44-47 ◽  
Author(s):  
Yi Jun Zhang ◽  
Xiao Zhen Shen ◽  
Sheng Yong Liu

In order to analyze the content of fatty acid methyl esters, biodiesel was analyzed by gas chromatography method. Biodiesel was produced from the raw materials soybean oil and mussel shell catalysts. GC analysis was developed by using HP-innowax chromatographic column and FID detector. Undecanoic acid methyl ester was chosen as internal standard solution. The results show that five kinds of fatty acid methyl esters were linear at range 4 g•L-1~31 g•L-1 (γ≥0.9928). The average recovery rate was 98.28%~101.85%, and relative standard deviation was less than 0.31%. The coefficient of variance of precision was less than 1.59%. This GC method is simple, rapid and accurate and it will be the base for further research.


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