A durable nanocatalyst of potassium-doped iron-carbide/alumina for significant production of linear alpha olefins via Fischer-Tropsch synthesis

2018 ◽  
Vol 564 ◽  
pp. 190-198 ◽  
Author(s):  
Ji Chan Park ◽  
Sanha Jang ◽  
Geun Bae Rhim ◽  
Jin Hee Lee ◽  
Hyunkyoung Choi ◽  
...  
Keyword(s):  
Iron Carbide ◽  
Tropsch Synthesis ◽  
Fischer Tropsch ◽  
Fischer Tropsch Synthesis ◽  
Significant Production ◽  
Alpha Olefins

scholarly journals Unravelling the K-promotion effect in a highly active and stable Fe5C2 nanoparticle for catalytic linear alpha-olefin production

2021 ◽  
Author(s):  
Jin Hee Lee ◽  
Hack-Keun Lee ◽  
Kwangsoo Kim ◽  
Geunbae Rhim ◽  
Min Hye Youn ◽  
...  
Keyword(s):  
Value Added ◽  
Tropsch Synthesis ◽  
Fischer Tropsch ◽  
Promotion Effect ◽  
Fischer Tropsch Synthesis ◽  
Highly Active ◽  
Olefin Production ◽  
Alpha Olefin ◽  
K Promotion ◽  
Alpha Olefins

C5−C13 linear alpha() olefins (LAOs) are high-value-added chemicals acknowledged by industry. However, using catalysts to elevate the activity and selectivity of LAOs remains a major challenge for Fischer–Tropsch synthesis (FTS)....

scholarly journals Back Cover: Selective Formation of Hägg Iron Carbide with g-C3 N4 as a Sacrificial Support for Highly Active Fischer-Tropsch Synthesis (ChemCatChem 21/2015)

ChemCatChem ◽  
2015 ◽  
Vol 7 (21) ◽  
pp. 3594-3594
Author(s):  
Hunmin Park ◽  
Duck Hyun Youn ◽  
Jae Young Kim ◽  
Won Yong Kim ◽  
Yo Han Choi ◽  
...  
Keyword(s):  
Iron Carbide ◽  
Tropsch Synthesis ◽  
Fischer Tropsch ◽  
Fischer Tropsch Synthesis ◽  
Back Cover ◽  
Highly Active ◽  
Selective Formation

scholarly journals Atomically Defined Iron Carbide Surface for Fischer–Tropsch Synthesis Catalysis

ACS Catalysis ◽  
2018 ◽  
Vol 9 (2) ◽  
pp. 1264-1273 ◽  
Author(s):  
Yijia Li ◽  
Zheshen Li ◽  
Ali Ahsen ◽  
Lutz Lammich ◽  
Gilbère J. A. Mannie ◽  
...  
Keyword(s):  
Iron Carbide ◽  
Tropsch Synthesis ◽  
Fischer Tropsch ◽  
Fischer Tropsch Synthesis

Selective Formation of Hägg Iron Carbide with g-C3N4as a Sacrificial Support for Highly Active Fischer-Tropsch Synthesis

ChemCatChem ◽  
2015 ◽  
Vol 7 (21) ◽  
pp. 3488-3494 ◽  
Author(s):  
Hunmin Park ◽  
Duck Hyun Youn ◽  
Jae Young Kim ◽  
Won Yong Kim ◽  
Yo Han Choi ◽  
...  
Keyword(s):  
Iron Carbide ◽  
Tropsch Synthesis ◽  
Fischer Tropsch ◽  
Fischer Tropsch Synthesis ◽  
Highly Active ◽  
Selective Formation

The effect of pore size or iron particle size on the formation of light olefins in Fischer–Tropsch synthesis

RSC Advances ◽  
2015 ◽  
Vol 5 (37) ◽  
pp. 29002-29007 ◽  
Author(s):  
Yi Liu ◽  
Jian-Feng Chen ◽  
Yi Zhang
Keyword(s):  
Particle Size ◽  
Pore Size ◽  
Carbide Particle ◽  
Iron Carbide ◽  
Iron Particle ◽  
Tropsch Synthesis ◽  
Light Olefins ◽  
Fischer Tropsch ◽  
Fischer Tropsch Synthesis

Smaller iron or iron carbide particle was advantageous to form more light olefins and O/P of C2–C4 was more sensitive to pore size of catalysts.

The role of carbon atoms of supported iron carbides in Fischer–Tropsch synthesis

2015 ◽  
Vol 5 (3) ◽  
pp. 1433-1437 ◽  
Author(s):  
V. V. Ordomsky ◽  
B. Legras ◽  
K. Cheng ◽  
S. Paul ◽  
A. Y. Khodakov
Keyword(s):  
Reaction Rate ◽  
Iron Carbide ◽  
High Reactivity ◽  
Tropsch Synthesis ◽  
Chain Growth ◽  
Fischer Tropsch ◽  
Iron Carbides ◽  
Fischer Tropsch Synthesis ◽  
Supported Iron

High reactivity of iron carbides enhances the Fischer–Tropsch reaction rate on supported iron catalysts. Carbon atoms in iron carbide are involved in the initiation of chain growth in Fischer–Tropsch synthesis.

scholarly journals Preparation of Iron Carbides Formed by Iron Oxalate Carburization for Fischer–Tropsch Synthesis

Catalysts ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 347
Author(s):  
Yang ◽  
Zhang ◽  
Liu ◽  
Ning ◽  
Han ◽  
...  
Keyword(s):  
Iron Carbide ◽  
Carbon Layer ◽  
Tropsch Synthesis ◽  
Light Olefins ◽  
Fischer Tropsch ◽  
Iron Carbides ◽  
Oxalate Precursor ◽  
Fischer Tropsch Synthesis ◽  
Iron Oxalate ◽  
In Situ Activation

Different iron carbides were synthesized from the iron oxalate precursor by varying the CO carburization temperature between 320 and 450 °C. These iron carbides were applied to the high-temperature Fischer–Tropsch synthesis (FTS) without in situ activation treatment directly. The iron oxalate as a precursor was prepared using a solid-state reaction treatment at room temperature. Pure Fe5C2 was formed at a carburization temperature of 320 C, whereas pure Fe3C was formed at 450 °C. Interestingly, at intermediate carburization temperatures (350–375 °C), these two phases coexisted at the same time although in different proportions, and 360 °C was the transition temperature at which the iron carbide phase transformed from the Fe5C2 phase to the Fe3C phase. The results showed that CO conversions and products selectivity were affected by both the iron carbide phases and the surface carbon layer. CO conversion was higher (75–96%) when Fe5C2 was the dominant iron carbide. The selectivity to C5+ products was higher when Fe3C was alone, while the light olefins selectivity was higher when the two components (Fe5C2 and Fe3C phases) co-existed, but the quantity of Fe3C was small.

scholarly journals The Effect of Copper Loading on Iron Carbide Formation and Surface Species in Iron-Based Fischer-Tropsch Synthesis Catalysts

ChemCatChem ◽  
2018 ◽  
Vol 10 (6) ◽  
pp. 1300-1312 ◽  
Author(s):  
Diego Peña ◽  
Lise Jensen ◽  
Andrea Cognigni ◽  
Rune Myrstad ◽  
Thomas Neumayer ◽  
...  
Keyword(s):  
Iron Carbide ◽  
Tropsch Synthesis ◽  
Carbide Formation ◽  
Surface Species ◽  
Fischer Tropsch ◽  
Fischer Tropsch Synthesis ◽  
Synthesis Catalysts ◽  
Iron Based ◽  
Effect Of Copper
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