Mechanistic insight into the reaction pathway of peroxomonosulfate-initiated decomplexation of EDTA-NiII under alkaline conditions: Formation of high-valent Ni intermediate

2021 ◽  
pp. 120375
Author(s):  
Sheng Liang ◽  
Xiaoting Hu ◽  
Haolin Xu ◽  
Zhenchao Lei ◽  
Chaohai Wei ◽  
...  
Keyword(s):  
Reaction Pathway ◽  
Mechanistic Insight ◽  
Alkaline Conditions ◽  
High Valent ◽  
Insight Into

Mechanistic Insight into the Aromatic Hydroxylation by High-Valent Iron(IV)-oxo Porphyrin π-Cation Radical Complexes

2007 ◽  
Vol 72 (16) ◽  
pp. 6301-6304 ◽  
Author(s):  
Min-Jung Kang ◽  
Woon Ju Song ◽  
Ah-Rim Han ◽  
Young S. Choi ◽  
Ho G. Jang ◽  
...  
Keyword(s):  
Cation Radical ◽  
Mechanistic Insight ◽  
Aromatic Hydroxylation ◽  
High Valent ◽  
Insight Into

Mechanistic Insight into Alcohol Oxidation by High-Valent Iron-Oxo Complexes of Heme and Nonheme Ligands

2005 ◽  
Vol 44 (27) ◽  
pp. 4235-4239 ◽  
Author(s):  
Na Young Oh ◽  
Yumi Suh ◽  
Mi Joo Park ◽  
Mi Sook Seo ◽  
Jinheung Kim ◽  
...  
Keyword(s):  
Alcohol Oxidation ◽  
Oxo Complexes ◽  
Mechanistic Insight ◽  
High Valent ◽  
Insight Into

DFT Studies Provide Mechanistic Insight into Nickel-Catalyzed Cross-Coupling Involving Organoaluminum-Mediated C–O Bond Cleavage

Synlett ◽  
2017 ◽  
Vol 28 (19) ◽  
pp. 2565-2568 ◽  
Author(s):  
Chao Wang ◽  
Masanobu Uchiyama ◽  
Ze-Kun Yang
Keyword(s):  
Density Functional ◽  
Reaction Pathway ◽  
Bond Cleavage ◽  
Cross Coupling ◽  
Reductive Elimination ◽  
Lewis Acidity ◽  
Functional Theory ◽  
Mechanistic Insight ◽  
Insight Into ◽  
Strong Lewis Acidity

Density functional theory (DFT) calculations were performed to examine the reaction pathway of Ni-catalyzed cross-coupling with organoaluminum through C–O bond cleavage. The results indicate that the strong Lewis acidity of organoaluminums significantly facilitates the transmetalation step, but not the oxidative addition or reductive elimination step.

Mechanistic Insight into Alcohol Oxidation by High-Valent Iron-Oxo Complexes of Heme and Nonheme Ligands

2005 ◽  
Vol 117 (27) ◽  
pp. 4307-4311 ◽  
Author(s):  
Na Young Oh ◽  
Yumi Suh ◽  
Mi Joo Park ◽  
Mi Sook Seo ◽  
Jinheung Kim ◽  
...  
Keyword(s):  
Alcohol Oxidation ◽  
Oxo Complexes ◽  
Mechanistic Insight ◽  
High Valent ◽  
Insight Into

Direct Synthesis of High-Valent Aryl–Cu(II) and Aryl–Cu(III) Compounds: Mechanistic Insight into Arene C–H Bond Metalation

2014 ◽  
Vol 136 (17) ◽  
pp. 6326-6332 ◽  
Author(s):  
Hu Zhang ◽  
Bo Yao ◽  
Liang Zhao ◽  
De-Xian Wang ◽  
Bo-Qing Xu ◽  
...  
Keyword(s):  
Direct Synthesis ◽  
Mechanistic Insight ◽  
High Valent ◽  
Insight Into
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