Mechanistic Insight into the Aromatic Hydroxylation by High-Valent Iron(IV)-oxo Porphyrin π-Cation Radical Complexes

2007 ◽  
Vol 72 (16) ◽  
pp. 6301-6304 ◽  
Author(s):  
Min-Jung Kang ◽  
Woon Ju Song ◽  
Ah-Rim Han ◽  
Young S. Choi ◽  
Ho G. Jang ◽  
...  
Keyword(s):  
Cation Radical ◽  
Mechanistic Insight ◽  
Aromatic Hydroxylation ◽  
High Valent ◽  
Insight Into

Mechanistic Insight into Alcohol Oxidation by High-Valent Iron-Oxo Complexes of Heme and Nonheme Ligands

2005 ◽  
Vol 44 (27) ◽  
pp. 4235-4239 ◽  
Author(s):  
Na Young Oh ◽  
Yumi Suh ◽  
Mi Joo Park ◽  
Mi Sook Seo ◽  
Jinheung Kim ◽  
...  
Keyword(s):  
Alcohol Oxidation ◽  
Oxo Complexes ◽  
Mechanistic Insight ◽  
High Valent ◽  
Insight Into

Mechanistic Insight into Alcohol Oxidation by High-Valent Iron-Oxo Complexes of Heme and Nonheme Ligands

2005 ◽  
Vol 117 (27) ◽  
pp. 4307-4311 ◽  
Author(s):  
Na Young Oh ◽  
Yumi Suh ◽  
Mi Joo Park ◽  
Mi Sook Seo ◽  
Jinheung Kim ◽  
...  
Keyword(s):  
Alcohol Oxidation ◽  
Oxo Complexes ◽  
Mechanistic Insight ◽  
High Valent ◽  
Insight Into

Direct Synthesis of High-Valent Aryl–Cu(II) and Aryl–Cu(III) Compounds: Mechanistic Insight into Arene C–H Bond Metalation

2014 ◽  
Vol 136 (17) ◽  
pp. 6326-6332 ◽  
Author(s):  
Hu Zhang ◽  
Bo Yao ◽  
Liang Zhao ◽  
De-Xian Wang ◽  
Bo-Qing Xu ◽  
...  
Keyword(s):  
Direct Synthesis ◽  
Mechanistic Insight ◽  
High Valent ◽  
Insight Into

scholarly journals Mechanistic insight into B(C6F5)3 catalyzed imine reduction with PhSiH3 under stoichiometric water conditions

RSC Advances ◽  
2021 ◽  
Vol 11 (34) ◽  
pp. 20961-20969
Author(s):  
Yunqing He ◽  
Wanli Nie ◽  
Ying Xue ◽  
Qishan Hu
Keyword(s):  
Mechanistic Insight ◽  
Excess Water ◽  
Water Conditions ◽  
Imine Reduction ◽  
Water Amount ◽  
Insight Into

Hydrosilylation or amination products? It depends on water amount and nucleophiles like excess water or produced/added amines.

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