An experimental study for rate constants of the gas phase reactions of CH3CH2OOH with OH radicals, O3, NO2 and NO

2008 ◽  
Vol 42 (27) ◽  
pp. 6614-6619 ◽  
Author(s):  
Caixia Wang ◽  
Zhongming Chen
Keyword(s):  
Experimental Study ◽  
Gas Phase ◽  
Rate Constants ◽  
Oh Radicals ◽  
Gas Phase Reactions

An experimental study of the reactivity of the hydroxide anion in the gas phase at room temperature, and its perturbation by hydration

1981 ◽  
Vol 59 (11) ◽  
pp. 1615-1621 ◽  
Author(s):  
Scott D. Tanner ◽  
Gervase I. Mackay ◽  
Diethard K. Bohme
Keyword(s):  
Experimental Study ◽  
Proton Transfer ◽  
Gas Phase ◽  
Rate Constants ◽  
Room Temperature ◽  
Gas Phase Reactions ◽  
Flowing Afterglow ◽  
Hydroxide Anion

Flowing afterglow measurements are reported which provide rate constants and product identifications at 298 ± 2 K for the gas-phase reactions of OH− with CH3OH, C2H5OH, CH3OCH3, CH2O, CH3CHO, CH3COCH3, CH2CO, HCOOH, HCOOCH3, CH2=C=CH2, CH3—C≡CH, and C6H5CH3. The main channels observed were proton transfer and solvation of the OH−. Hydration with one molecule of H2O was observed either to reduce the rate slightly and lead to products which are the hydrated analogues of the "nude" reaction, or to stop the reaction completely, k ≤ 10−12 cm3 molecule−1 s−1. The reaction of OH−•H2O with CH3—C≡CH showed an uncertain intermediate behaviour.

Rate constants of the gas-phase reactions of OH radicals withtrans-2-hexenal,trans-2-octenal, andtrans-2-nonenal

2009 ◽  
Vol 41 (7) ◽  
pp. 483-489 ◽  
Author(s):  
Tingting Gao ◽  
Jean M. Andino ◽  
Carlos C. Rivera ◽  
Misaela Francisco Márquez
Keyword(s):  
Gas Phase ◽  
Rate Constants ◽  
Oh Radicals ◽  
Gas Phase Reactions

Rate constants for the gas-phase reactions of cyclo-CXCXCF2CF2– (X=H, F) with OH radicals at a temperature range of 253–328K

2013 ◽  
Vol 572 ◽  
pp. 21-25 ◽  
Author(s):  
Xiaoqing Jia ◽  
Liang Chen ◽  
Junji Mizukado ◽  
Shuzo Kutsuna ◽  
Kazuaki Tokuhashi
Keyword(s):  
Gas Phase ◽  
Rate Constants ◽  
Oh Radicals ◽  
Gas Phase Reactions ◽  
Temperature Range
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