Effects of calcination temperatures on the catalytic performance of Rh/Al2O3 for methane partial oxidation to synthesis gas

2006 ◽  
Vol 117 (1-3) ◽  
pp. 53-61 ◽  
Author(s):  
W WENG ◽  
X PEI ◽  
J LI ◽  
C LUO ◽  
Y LIU ◽  
...  
2000 ◽  
Vol 61 (1-4) ◽  
pp. 237-242 ◽  
Author(s):  
Wen-Shu Yang ◽  
Hong-Wie Xiang ◽  
Yong-Wang Li ◽  
Yu-Han Sun

1996 ◽  
Vol 32 (1-4) ◽  
pp. 149-156 ◽  
Author(s):  
M.A. Goula ◽  
A.A. Lemonidou ◽  
W. Grünert ◽  
M. Baerns

2011 ◽  
Vol 284-286 ◽  
pp. 1905-1908
Author(s):  
Bao Song Fu ◽  
Hu Liu ◽  
Guo Min Xiao

Narrow size distribution Palladium nanoparticles was synthesized by adding Pd precursor into a modified PMHS polymer solution, and then jelled by aluminium. The multi-functional polymer was characterized by NMR; Pd nanoparticle samples were characterized by TEM and catalytic activity was tested in methane partial oxidation reaction.


Catalysts ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 479 ◽  
Author(s):  
Yuyao Ma ◽  
Yuxia Ma ◽  
Min Liu ◽  
Yang Chen ◽  
Xun Hu ◽  
...  

Electrospinning is a simple and efficient technique for fabricating fibrous catalysts. The effects of preparation parameters on catalyst performance were investigated on fibrous Ni/Al2O3 catalysts. The catalyst prepared with H2O/C2H5OH solvent showed higher catalytic activity than that with DMF/C2H5OH solvent because of the presence of NiO in the catalyst prepared with DMF/C2H5OH solvent. The metal ion content of the precursor also influences catalyst properties. In this work, the Ni/Al2O3 catalyst prepared with a solution containing the metal ion content of 30 wt % demonstrated the highest Ni dispersion and therefore the highest catalytic performance. Additionally, the Ni dispersion decreased as calcination temperature was enhanced from 700 to 900 °C due to the increased Ni particle sizes, which also caused a high reduction temperature and low catalytic activity in methane partial oxidation. Finally, the fibrous Ni/Al2O3 catalysts can achieve high syngas yields at high reaction temperatures and high gas flow rates.


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