Continuous flow carbamoylation of aniline by dimethyl carbonate using a microreactor coated with a thin film of ceria supported gold nanoparticles

2011 ◽  
Vol 159 (1) ◽  
pp. 25-28 ◽  
Author(s):  
Raquel Juárez ◽  
Helmut Pennemann ◽  
Hermenegildo García
2011 ◽  
Vol 84 (3) ◽  
pp. 685-694 ◽  
Author(s):  
Raquel Juárez ◽  
Avelino Corma ◽  
Hermenegildo García

Aliphatic amines react sluggishly with dimethyl carbonate (DMC) to give a mixture of N-methylation and carbamoylation. Nanoparticulated ceria as catalyst increases, in general, conversion and selectivity toward carbamoylation. This increase in catalytic activity and selectivity toward carbamoylation is even increased by deposition of Au nanoparticles on ceria. However, in contrast to aromatic amines for which a complete selectivity toward carbamoylation using ceria-supported Au nanoparticles can be achieved, the catalytic carbamoylation of aliphatic amines by ceria-supported Au nanoparticles occurs only with moderate selectivity.


2017 ◽  
Vol 5 (6) ◽  
pp. 4746-4756 ◽  
Author(s):  
Barbara Ballarin ◽  
Davide Barreca ◽  
Elisa Boanini ◽  
Maria Cristina Cassani ◽  
Paolo Dambruoso ◽  
...  

2011 ◽  
Vol 167 (2-3) ◽  
pp. 519-526 ◽  
Author(s):  
Lahbib Abahmane ◽  
Andrea Knauer ◽  
J. Michael Köhler ◽  
G. Alexander Groß

2018 ◽  
Vol 122 (44) ◽  
pp. 25456-25466 ◽  
Author(s):  
Jing-Jing Li ◽  
Bao-Lin Zhu ◽  
Gui-Chang Wang ◽  
Zun-Feng Liu ◽  
Wei-Ping Huang ◽  
...  

ChemCatChem ◽  
2017 ◽  
Vol 9 (7) ◽  
pp. 1354-1354
Author(s):  
Luísa Margarida Dias Ribeiro de Sousa Martins ◽  
Sónia Alexandra Correia Carabineiro ◽  
Jiawei Wang ◽  
Bruno Gonçalo Martins Rocha ◽  
Francisco José Maldonado-Hódar ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document