Highly selective synthesis of methanol from methane over carbon materials supported Pd-Au nanoparticles under mild conditions

A convenient, transition-metal-free access to a series of unprecedented saccharin substituted 2,5-dihydropyrroles is reported. This approach employs a post-Ugi-Smiles 5-endo-dig Conia-ene cyclization sequence in mild conditions while incorporating a series...

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Efficient hydrogenolysis of aryl ethers over Ce-MOF supported Pd NPs under mild conditions: mechanistic insight using density functional theoretical calculations

Catalysis Science & Technology ◽

10.1039/d0cy01279c ◽

2020 ◽

Vol 10 (20) ◽

pp. 6892-6901

Author(s):

Ashish Kumar Kar ◽

Surinder Pal Kaur ◽

T. J. Dhilip Kumar ◽

Rajendra Srivastava

Keyword(s):

Catalytic Activity ◽

Adsorption Energy ◽

Density Functional ◽

Theoretical Calculations ◽

Desorption Energy ◽

Mild Conditions ◽

Mechanistic Insight ◽

Aryl Ethers ◽

Benzyl Phenyl Ether ◽

Supported Pd

The significant Pd0 content and optimum bonding of the reactant & product (higher adsorption energy of benzyl phenyl ether and lower desorption energy for phenol) are responsible for the exceptional catalytic activity of Pd/Ce-MOF.

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Cycloisomerization of Conjugated Allenones into Furans under Mild Conditions Catalyzed by Ligandless Au Nanoparticles

Organic Letters ◽

10.1021/acs.orglett.9b01869 ◽

2019 ◽

Vol 21 (14) ◽

pp. 5552-5555 ◽

Cited By ~ 12

Author(s):

Leandros Zorba ◽

Marios Kidonakis ◽

Iakovos Saridakis ◽

Manolis Stratakis

Keyword(s):

Au Nanoparticles ◽

Mild Conditions

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Catalytic Performance of Carbon Materials Supported Pd Nanoparticles in Selective Hydrogenation of Acetylene

Chinese Journal of Chemical Physics ◽

10.1063/1674-0068/30/cjcp1704082 ◽

2017 ◽

Vol 30 (5) ◽

pp. 559-565 ◽

Cited By ~ 4

Author(s):

Fan-fan Yao ◽

Yu-jia Huo ◽

Yun-sheng Ma

Keyword(s):

Selective Hydrogenation ◽

Carbon Materials ◽

Pd Nanoparticles ◽

Catalytic Performance ◽

Selective Hydrogenation Of Acetylene ◽

Supported Pd

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Substrate selective synthesis of pyrazolo[1,5-a]pyridines through [3 + 2] cycloaddition of N-aminopyridines and β-nitro styrenes

RSC Advances ◽

10.1039/c5ra06707c ◽

2015 ◽

Vol 5 (53) ◽

pp. 42961-42964 ◽

Cited By ~ 9

Author(s):

Chitrakar Ravi ◽

Darapaneni Chandra Mohan ◽

N. Naresh Kumar Reddy ◽

Subbarayappa Adimurthy

Keyword(s):

Selective Synthesis ◽

Metal Free ◽

Mild Conditions

Synthesis of 2 or 3-(hetero)aryl pyrazolo[1,5-a]pyridines through [3 + 2] cycloaddition ofN-aminopyridine with β-nitrostyrenes followed byin situdenitration under metal-free and mild conditions are described.

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Methyl ester synthesis catalyzed by nanoporous gold: from 10−9 Torr to 1 atm

Catalysis Science & Technology ◽

10.1039/c4cy01169d ◽

2015 ◽

Vol 5 (2) ◽

pp. 1299-1306 ◽

Cited By ~ 16

Author(s):

Lu-Cun Wang ◽

Kara J. Stowers ◽

Branko Zugic ◽

Monika M. Biener ◽

Juergen Biener ◽

...

Keyword(s):

Methyl Ester ◽

Oxidative Coupling ◽

Pressure Range ◽

Methyl Esters ◽

Nanoporous Gold ◽

Selective Synthesis ◽

Ester Synthesis ◽

Mild Conditions ◽

Wide Pressure Range ◽

Wide Pressure

Highly selective synthesis of methyl esters can be achieved by oxidative coupling of methanol and aldehydes (acetaldehyde, butyraldehyde) under mild conditions using unsupported nanoporous gold catalysts over a wide pressure range (from 10−9 Torr to 1 atm).

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