Synthesis of two new cage molecules containing trinitromethyl group

2010 ◽  
Vol 21 (5) ◽  
pp. 572-575 ◽  
Author(s):  
Cheng Hui Sun ◽  
Xin Qi Zhao ◽  
Yu Chuan Li ◽  
Si Ping Pang
Keyword(s):  
Cage Molecules ◽  
Trinitromethyl Group

Controlling Gas Selectivity in Molecular Porous Liquids by Tuning the Cage Window Size

2019 ◽  
Author(s):  
Benjamin Egleston ◽  
Konstantin V. Luzyanin ◽  
Michael C. Brand ◽  
Rob Clowes ◽  
Michael E. Briggs ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Chemical Synthesis ◽  
Field Gradient ◽  
Window Size ◽  
Standard Approach ◽  
Porous Solids ◽  
Pulsed Field Gradient Nmr ◽  
Pulsed Field ◽  
Cage Molecules ◽  
Gas Selectivity

Control of pore window size is the standard approach for tuning gas selectivity in porous solids. Here, we present the first example where this is translated into a molecular porous liquid formed from organic cage molecules. Reduction of the cage window size by chemical synthesis switches the selectivity from Xe-selective to CH<sub>4</sub>-selective, which is understood using <sup>129</sup>Xe, <sup>1</sup>H, and pulsed-field gradient NMR spectroscopy.

Controlling Gas Selectivity in Molecular Porous Liquids by Tuning the Cage Window Size

2019 ◽  
Author(s):  
Benjamin Egleston ◽  
Konstantin V. Luzyanin ◽  
Michael C. Brand ◽  
Rob Clowes ◽  
Michael E. Briggs ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Chemical Synthesis ◽  
Field Gradient ◽  
Window Size ◽  
Standard Approach ◽  
Porous Solids ◽  
Pulsed Field Gradient Nmr ◽  
Pulsed Field ◽  
Cage Molecules ◽  
Gas Selectivity

Control of pore window size is the standard approach for tuning gas selectivity in porous solids. Here, we present the first example where this is translated into a molecular porous liquid formed from organic cage molecules. Reduction of the cage window size by chemical synthesis switches the selectivity from Xe-selective to CH<sub>4</sub>-selective, which is understood using <sup>129</sup>Xe, <sup>1</sup>H, and pulsed-field gradient NMR spectroscopy.

Synthesis of Organic Photodimeric Cage Molecules Based on Cycloaddition via Metal−Ligand Directed Assembly

2007 ◽  
Vol 129 (18) ◽  
pp. 5820-5821 ◽  
Author(s):  
Jarrod F. Eubank ◽  
Victor Ch. Kravtsov ◽  
Mohamed Eddaoudi
Keyword(s):  
Directed Assembly ◽  
Cage Molecules ◽  
Metal Ligand

scholarly journals Metallophilicity-assisted assembly of phosphine-based cage molecules

2014 ◽  
Vol 43 (16) ◽  
pp. 6236 ◽  
Author(s):  
Julia R. Shakirova ◽  
Elena V. Grachova ◽  
Antti J. Karttunen ◽  
Vladislav V. Gurzhiy ◽  
Sergey P. Tunik ◽  
...  
Keyword(s):  
Cage Molecules

Synthesis and rearrangement of strained cage molecules

1971 ◽  
Vol 93 (6) ◽  
pp. 1446-1452 ◽  
Author(s):  
William G. Dauben ◽  
Charles H. Schallhorn ◽  
Dale L. Whalen
Keyword(s):  
Cage Molecules

Icosahedral symmetry carbon cage molecules

Nature ◽  
1986 ◽  
Vol 323 (6090) ◽  
pp. 703-706 ◽  
Author(s):  
D. J. Klein ◽  
W. A. Seitz ◽  
T. G. Schmalz
Keyword(s):  
Icosahedral Symmetry ◽  
Carbon Cage ◽  
Cage Molecules
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