In situ synthesis of α-alumina layer at top yttrium-stabilized zirconia thermal barrier coatings for oxygen barrier

2014 ◽  
Vol 40 (8) ◽  
pp. 12703-12708 ◽  
Author(s):  
Xiao-feng Zhang ◽  
Ke-song Zhou ◽  
Xu Wei ◽  
Bo-yu Chen ◽  
Jin-bing Song ◽  
...  
Author(s):  
Anders Thibblin ◽  
Siamak Kianzad ◽  
Stefan Jonsson ◽  
Ulf Olofsson

Thermal barrier coatings have the potential to improve the fuel efficiency of heavy-duty diesel engines by reducing heat losses. A method for in-situ measurement of heat flux from the combustion chamber of a heavy-duty diesel engine has been developed and was used to study the running-in behaviour of different thermal barrier coating materials and types of microstructures. The in-situ measurements show that the initial heat flux was reduced by up to 4.7% for all investigated thermal barrier coatings compared to a steel reference, except for an yttria-stabilized zirconia coating with sealed pores that had an increase of 12.0% in heat flux. Gd2Zr2O7 had the lowest initial value for heat flux. However, running-in shows the lowest values for yttria-stabilized zirconia after 2–3 h. Potential spallation problems were observed for Gd2Zr2O7 and La2Zr2O7.


2005 ◽  
Vol 492-493 ◽  
pp. 379-384 ◽  
Author(s):  
Klod Kokini ◽  
Sudarshan V. Rangaraj

The thermal fracture and its dependence on time-dependent behavior in functionally graded yttria stabilized zirconia - NiCoCrAlY bond coat alloy thermal barrier coatings was studied. The response of three coating architectures of similar thermal resistance to laser thermal shock tests was considered, experimentally and computationally.


2021 ◽  
Vol 320 ◽  
pp. 31-36
Author(s):  
Marek Góral ◽  
Tadeusz Kubaszek ◽  
Barbara Kościelniak ◽  
Marcin Drajewicz ◽  
Mateusz Gajewski

Thermal barrier coatings are widely used for protection of gas turbine parts against high temperature oxidation and hot corrosion. In present work the microstructural assessment of TBCs produced by atmospheric plasma spray (APS) method was conducted. Three types of ceramic powders were used: magnesia- stabilized zirconia oxide (Metco 210), yttria stabilized zirconia oxide (YSZ -Metco 204) and fine-grained YSZ – Metco 6700. As a base material the Inconel 713 was used as well and CoNiCrAlY was plasma sprayed (APS) as a bond coat. The thickness of all ceramic layers was in range 80 – 110 μm. The elemental mapping of cross-section of magnesia-stabilized zirconia showed the presence of Mg, Zr and O in outer layer. In the YSZ ceramic layer the Y, Zr and O were observed during elemental mapping. The isothermal oxidation test was conducted at 1100 °C for 500 h in static laboratory air. On all samples the delamination and spallation of ceramic layers was observed. Chemical composition analysis of coatings showed the presence of two areas: the first one contained elements from bond coats: Ni, Cr, Al, Co and second area contained O, Cr Co and O that suggest the scale formation. The obtained results showed the total degradation of all ceramic layers as a result of internal stresses in bond-coat. Microscopic analysis showed the areas with complete degradation of bond coats and formation of thick oxides layer.


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