Rare earth elements in drill cutting samples from off-shore oil and gas exploration activities in ultradeep waters

Chemosphere ◽  
2021 ◽  
Vol 263 ◽  
pp. 127984
Author(s):  
Klaiani Bez Fontana ◽  
Rennan Geovanny O. Araujo ◽  
Fernando J.S. de Oliveira ◽  
Vera L.A.F. Bascuñan ◽  
Tatiane de Andrade Maranhão
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Oil And Gas ◽  
Oil And Gas Exploration ◽  
Drill Cutting

Extraction concentrating of the acid-soluble forms of rare earth elements from oils of the Volga-Ural oil and gas province using rotating coiled columns

2021 ◽  
Vol 87 (12) ◽  
pp. 5-10
Author(s):  
E. Yu. Savonina ◽  
O. N. Katasonova ◽  
T. A. Maryutina
Keyword(s):  
Trace Elements ◽  
Rare Earth ◽  
Rare Earth Elements ◽  
Inductively Coupled Plasma ◽  
Oil And Gas ◽  
Direct Determination ◽  
Soluble Form ◽  
Rotating Coiled Columns ◽  
Wide Range

Trace elements in oils are the natural markers of the oil origin of and the mechanism of oil genesis. Direct determination of rare earth elements (REE) in crude oils is rather difficult due to their low concentrations (10–6 wt. %). Information about the forms of trace elements in oils is of particular interest. The goal of the study is determination of the content of acid-soluble forms of REE in oils from various fields of the Volga-Ural oil and gas province. Six samples of oils of heavy and medium density and viscosity were analyzed. Extraction of acid-soluble forms of REE was carried out using rotating coiled columns in 0.5 M aqueous solution of nitric acid. Toluene was used to dilute the oils up to the necessary values of the density and viscosity providing the possibility of extraction in the system aqueous acid solution – oil. The content of REE was determined by inductively coupled plasma mass spectrometry on an Agilent 7900 spectrometer. Their content in an acid-soluble form in oil samples under study ranged within 172 – 2173 ng/kg. Such a wide range of values is attributed to the difference in the geology and age of deposit formation. The highest content of acid-soluble forms of REE (2173 ng/kg) was observed in the oil sample from the Novo-Elkhovsky field, whereas the lowest value (172 ng/kg) was measured in the oil sample of the Pioneer field. It is shown that the content of acid-soluble forms of REE depends on tectonic zoning, productive horizons and layers, as well as on the physical and chemical properties of oils. The distribution of acid-soluble forms of light and heavy REE was evaluated. Most of the REE (75 – 99%) determined in the analyzed oil samples are light REE. It is noted that systematization of the data on the properties of oils, geological and geochemical characteristics of the deposits will provide reliable forecasting of the various forms of REE present in oils.

Flame spectra of the rare-earth elements*

1962 ◽  
Vol 18 (4) ◽  
pp. 1127-1153
Author(s):  
V FASSEL ◽  
R CURRY ◽  
R KNISELEY
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
The Rare Earth

ESTIMATION OF THE ABUNDANCE AND DISTRIBUTION OF RARE EARTH ELEMENTS IN SOIL AROUND KADUNA REFINING AND PETROCHEMICAL COMPANY USING NUCLEAR TECHNIQUE

2020 ◽  
Vol 4 (2) ◽  
pp. 599-604
Author(s):  
Michael A. Onoja ◽  
P. H. Bukar ◽  
C. U. Omeje ◽  
A. M. Adamu
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Nuclear Technique ◽  
Flood Plains ◽  
Economic Exploitation ◽  
Rare Elements ◽  
Petrochemical Company ◽  
The Moment ◽  
Abundance And Distribution ◽  
Natural Pattern

Instrumental neutron activation analysis (INAA) technique was used to investigate the abundance and distribution of rare earth elements (REE) in soil around Kaduna Refinery. The aim of the study is to assess the rare elements potential of Nigeria for economic exploitation. Five REEs (La, Dy, Eu, Yb, and Lu) were detected in varying concentrations ranging from a minimum of 0.6 µg/g (Lu) to a maximum of 249.0 µg/g (La). The elements existed with trends consistent with the natural pattern of REEs in soil, showing significant Eu and Dy anomalies which characterize upper plains and flood plains. The levels of REEs in soil in the study area were generally slightly above background levels, with minimal (La, Dy, and Eu), moderate (Yb), and significant (Lu) enrichments and trending: Lu ˃Yb ˃ Eu ˃ Dy ˃ La. The abundance of the REEs investigated cannot establish a potential of Nigeria for economic exploitation of the mineral, hence, rare earth project in the study area is not viable at the moment.

Sc, Y, La-Lu Rare Earth Elements

1986 ◽  
Author(s):  
Ingeborg Hinz ◽  
Peter Kuhn ◽  
Ursula Vetter ◽  
Eberhard Warkentin
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements
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