Time domain simulation of Li-ion batteries using non-integer order equivalent electrical circuit

2013 ◽  
Vol 18 (6) ◽  
pp. 1454-1462 ◽  
Author(s):  
D. Riu ◽  
M. Montaru ◽  
Y. Bultel
2011 ◽  
Vol 158 (3) ◽  
pp. A326 ◽  
Author(s):  
T. K. Dong ◽  
A. Kirchev ◽  
F. Mattera ◽  
J. Kowal ◽  
Y. Bultel

Energies ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4415
Author(s):  
Brian Ospina Agudelo ◽  
Walter Zamboni ◽  
Eric Monmasson

This paper is a comparative study of the multiple RC, Oustaloup and Grünwald–Letnikov approaches for time domain implementations of fractional-order battery models. The comparisons are made in terms of accuracy, computational burden and suitability for the identification of impedance parameters from time-domain measurements. The study was performed in a simulation framework and focused on a set of ZARC elements, representing the middle frequency range of Li-ion batteries’ impedance. It was found that the multiple RC approach offers the best accuracy–complexity compromise, making it the most interesting approach for real-time battery simulation applications. As for applications requiring the identification of impedance parameters, the Oustaloup approach offers the best compromise between the goodness of the obtained frequency response and the accuracy–complexity requirements.


Author(s):  
Д.А. Ложкина ◽  
А.М. Румянцев ◽  
Е.В. Астрова

Dry sintered macroporous Si electrodes for Li-ion batteries are first studied using spectral impedance measurements (EIS). The obtained EIS spectra in the lithiated and delithated state are modeled by an equivalent electrical circuit, the parameters of which make it possible to determine the main stages of the electrochemical process of lithium incorporation / extraction caused by the surface layer of solid-state electrolyte (SEI), a double electric layer, and diffusion in the solid phase of the electrode material. It was shown that the effective diffusion coefficient of Li in Si increases with rising degree of lithiation from D = 6.5·10 ^ (-12) cm2/s to D = 2.6·10^ (-10) cm2/s. The effect of carbonization by sucrose pyrolysis was studied, which led to a decrease in impedance and an increase in the diffusion coefficient of lithium to D = 2.2·10^(-10) - 1.7·10^(-9) cm2/s.


2013 ◽  
Vol 221 ◽  
pp. 70-77 ◽  
Author(s):  
Jan Philipp Schmidt ◽  
Philipp Berg ◽  
Michael Schönleber ◽  
André Weber ◽  
Ellen Ivers-Tiffée

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