On the reactivity of trimethylgallium with H2O, CH3OH, CH3OCH3, and NH3 in a multiple pulsed nozzle environment

2004 ◽  
Vol 388 (1-3) ◽  
pp. 12-17 ◽  
Author(s):  
Michael Lynch ◽  
Alexander Demchuk ◽  
Steven Simpson ◽  
Brent Koplitz
Keyword(s):  
Pulsed Nozzle

Spectroscopic investigations of hydrogen bonding interactions in the gas phase. VIII. Microwave rotational spectrum of the heterodimer H—C≡C—C≡N ∙ ∙ ∙ HF

1984 ◽  
Vol 394 (1807) ◽  
pp. 387-403 ◽  
Keyword(s):  
Gas Phase ◽  
Continuous Wave ◽  
Spectroscopic Constants ◽  
State Transitions ◽  
Rotational Spectrum ◽  
Microwave Spectra ◽  
Hydrogen Bonding Interactions ◽  
Microwave Rotational Spectrum ◽  
Microwave Techniques ◽  
Pulsed Nozzle

The hydrogen bonded dimer formed between cyanoacetylene and hydrogen fluoride has been identified through its infrared and microwave spectra. Two microwave techniques, continuous wave and pulsed-nozzle Fourier-transform spectroscopy, have been combined to identify unambiguously the vibrational ground state transitions and to assign vibrational satellites. In making the assignments, much use has been made of computer simu­lation of spectra, which is described in an Appendix. Analysis of the microwave spectra led to the following spectroscopic constants and molecular parameters. HC 3 N ∙ ∙ ∙HF HC 3 N∙ ∙ ∙DF B 0 /MHz 1220.68431 (9) 1204.9051 (2) D J /kHz 0.306 (2) 0.296 (3) α β /MHz ─7.20 (2) — γ β /MHz 0.094 (3) — γ 11 /MHz ─0.030 (2) — α σ /MHz ─13.7 (2) — q β /MHz 3.12 (2) — r 0 (N ∙ ∙ ∙ F)/nm 0.2788 0.2785 X /MHz ─ 3.876 ─ 3.854 v β /cm -1 30 — v σ /cm -1 139 — k σ /(N m -1 ) 16.3 — k s /(N m -1 ) 770 — Finally, the variation of ∆ v̄ as a function of r 0 (N ∙ ∙ ∙ F) has been examined for a series of dimers RCN ∙ ∙ ∙ HF.

Toward Growing III-V Clusters with Metalorganic Precursors

1997 ◽  
Vol 468 ◽  
Author(s):  
A. Demchuk ◽  
J. Porter ◽  
B. Koplitz
Keyword(s):  
Excimer Laser ◽  
Vacuum Chamber ◽  
High Vacuum ◽  
Pulsed Laser ◽  
Quadrupole Mass ◽  
Reaction Region ◽  
High Vacuum Chamber ◽  
Arf Excimer Laser ◽  
193 Nm ◽  
Pulsed Nozzle

ABSTRACTThe present work reports on the formation of GaN-containing clusters from metalorganic precursors by combining pulsed laser photolysis and pulsed nozzle methods. Ammonia (NH3) and triethylgallium (C2H5)3Ga (TEG) or trimethylgallium (CH3)3Ga (TMG) with He, Ar, or N2 as the carrier gas are introduced into a high vacuum chamber via a specialized dual pulsed nozzle source. The light from an ArF excimer laser (193 nm, 23 ns FWHM) is focused into the mixing and reaction region of the nozzle source, and the products are then mass analyzed with a quadrupole mass spectrometer. Efficient laser-assisted growth of (GaN)x-containing clusters is shown with this technique.

scholarly journals Pulsed nozzle beam spectroscopy and synchrotron radiation.

1986 ◽  
Vol 35 (5) ◽  
pp. 419-420
Author(s):  
Yohji Achiba
Keyword(s):  
Synchrotron Radiation ◽  
Nozzle Beam ◽  
Pulsed Nozzle

Reanalysis of the Nuclear Quadrupole Coupling in the Rotational Spectrum of N-Methylpyrrole

1994 ◽  
Vol 49 (11) ◽  
pp. 1063-1066
Author(s):  
S. R. Huber ◽  
A. Bauder
Keyword(s):  
Fourier Transform ◽  
Coupling Constants ◽  
Rotational Spectrum ◽  
Centrifugal Distortion ◽  
Least Squares Fit ◽  
Quadrupole Coupling ◽  
Nuclear Quadrupole ◽  
Centrifugal Distortion Constants ◽  
Pulsed Nozzle ◽  
Measured Transition

Abstract The rotational spectrum of N-methylpyrrole has been measured with pulsed nozzle Fourier transform microwave spectrometers between 6 and 38 GHz. The quadrupole hyperfine structure due to 14N has been reanalyzed in the A (m = 0) state o f the methyl internal rotation. Improved rotational constants, centrifugal distortion constants, and quadrupole coupling constants have been simultaneously determined from the measured transition frequencies in an iterative least-squares fit.

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