Palaeomagnetic secular variation recorded by lavas from the Taupo Volcanic Zone, New Zealand

<p>In order to understand the origin, temporal behaviour and spatial characteristics of Earth’s magnetic field, globally distributed records of the palaeomagnetic direction and absolute palaeointensity are required. However a paucity of data from the southern hemisphere significantly limits the resolution of global field models, particularly on short time-scales. In this thesis new, high quality palaeomagnetic data from volcanic materials sampled within the Taupo Volcanic Zone, New Zealand are presented, with a focus on the Tongariro and Okataina Volcanic Centre. New palaeomagnetic directions were obtained from 19 andesitic or rhyolitic lavas, of which 10 also produced successful palaeointensity results. Palaeointensity experiments were conducted using a combination of traditional Thellier-type thermal, and microwave techniques. Detailed magneto-mineralogical investigations carried out alongside these experiments helped to characterise the primary remanence carriers and to justify the reliability of the results. The study also revises the age controls and results from earlier palaeomagnetic studies on Holocene volcanic materials from the area. All new or revised data are summarized into a new data compilation for New Zealand, which includes 24 directions and ten palaeointensities dated between 1886 AD and 15,000 yrs BP. The new directional data reproduces the features of the most recently published continuous record from Lake Mavora (Fiordland, New Zealand), although with directions ranging in their extremes from 321° (west) to 26° (east) declination and -82 to -49° in inclination, the discrete dataset describes somewhat larger amplitude swings. With few exceptions, the new palaeointensity dataset describes a steady increase in the palaeointensity throughout the Holocene, from 37.0 ± 5.7 μT obtained from a pre-8 ka lava to 70.6 ± 4.1 μT from the youngest (≤ 500 yrs BP) flows sampled. A similar trend is also predicted by the latest global field model pfm9k. Furthermore, the data falls within the range of palaeointensity variation suggested by the Mavora record. The dataset roughly agrees with a global VADM reconstruction in the early Holocene (> 5000 yrs BP), but yields values significantly above the global trend in the late Holocene (< 1000 yrs BP) which supports the presence of significant non-dipolar components over the SW Pacific region in the time period, visible in global field models and from continuous PSV records. A comparison of the directional records with the Mavora Curve provided refinement of age estimates of five lava flows from the Tongariro Volcanic Centre, from uncertainties in the range of 2-3000 years. The new palaeomagnetic emplacement age estimates for these flows have age brackets as short as 500 years and thus highlight different phases of the young cone building eruptive activity on Ruapehu volcano.</p>

Palaeomagnetic secular variation recorded by lavas from the Taupo Volcanic Zone, New Zealand

<p>In order to understand the origin, temporal behaviour and spatial characteristics of Earth’s magnetic field, globally distributed records of the palaeomagnetic direction and absolute palaeointensity are required. However a paucity of data from the southern hemisphere significantly limits the resolution of global field models, particularly on short time-scales. In this thesis new, high quality palaeomagnetic data from volcanic materials sampled within the Taupo Volcanic Zone, New Zealand are presented, with a focus on the Tongariro and Okataina Volcanic Centre. New palaeomagnetic directions were obtained from 19 andesitic or rhyolitic lavas, of which 10 also produced successful palaeointensity results. Palaeointensity experiments were conducted using a combination of traditional Thellier-type thermal, and microwave techniques. Detailed magneto-mineralogical investigations carried out alongside these experiments helped to characterise the primary remanence carriers and to justify the reliability of the results. The study also revises the age controls and results from earlier palaeomagnetic studies on Holocene volcanic materials from the area. All new or revised data are summarized into a new data compilation for New Zealand, which includes 24 directions and ten palaeointensities dated between 1886 AD and 15,000 yrs BP. The new directional data reproduces the features of the most recently published continuous record from Lake Mavora (Fiordland, New Zealand), although with directions ranging in their extremes from 321° (west) to 26° (east) declination and -82 to -49° in inclination, the discrete dataset describes somewhat larger amplitude swings. With few exceptions, the new palaeointensity dataset describes a steady increase in the palaeointensity throughout the Holocene, from 37.0 ± 5.7 μT obtained from a pre-8 ka lava to 70.6 ± 4.1 μT from the youngest (≤ 500 yrs BP) flows sampled. A similar trend is also predicted by the latest global field model pfm9k. Furthermore, the data falls within the range of palaeointensity variation suggested by the Mavora record. The dataset roughly agrees with a global VADM reconstruction in the early Holocene (> 5000 yrs BP), but yields values significantly above the global trend in the late Holocene (< 1000 yrs BP) which supports the presence of significant non-dipolar components over the SW Pacific region in the time period, visible in global field models and from continuous PSV records. A comparison of the directional records with the Mavora Curve provided refinement of age estimates of five lava flows from the Tongariro Volcanic Centre, from uncertainties in the range of 2-3000 years. The new palaeomagnetic emplacement age estimates for these flows have age brackets as short as 500 years and thus highlight different phases of the young cone building eruptive activity on Ruapehu volcano.</p>

An Improved Cloud Gap-Filling Method for Longwave Infrared Land Surface Temperatures through Introducing Passive Microwave Techniques

Satellite-derived land surface temperature (LST) data are most commonly observed in the longwave infrared (LWIR) spectral region. However, such data suffer frequent gaps in coverage caused by cloud cover. Filling these ‘cloud gaps’ usually relies on statistical re-constructions using proximal clear sky LST pixels, whilst this is often a poor surrogate for shadowed LSTs insulated under cloud. Another solution is to rely on passive microwave (PM) LST data that are largely unimpeded by cloud cover impacts, the quality of which, however, is limited by the very coarse spatial resolution typical of PM signals. Here, we combine aspects of these two approaches to fill cloud gaps in the LWIR-derived LST record, using Kenya (East Africa) as our study area. The proposed “cloud gap-filling” approach increases the coverage of daily Aqua MODIS LST data over Kenya from <50% to >90%. Evaluations were made against the in situ and SEVIRI-derived LST data respectively, revealing root mean square errors (RMSEs) of 2.6 K and 3.6 K for the proposed method by mid-day, compared with RMSEs of 4.3 K and 6.7 K for the conventional proximal-pixel-based statistical re-construction method. We also find that such accuracy improvements become increasingly apparent when the total cloud cover residence time increases in the morning-to-noon time frame. At mid-night, cloud gap-filling performance is also better for the proposed method, though the RMSE improvement is far smaller (<0.3 K) than in the mid-day period. The results indicate that our proposed two-step cloud gap-filling method can improve upon performances achieved by conventional methods for cloud gap-filling and has the potential to be scaled up to provide data at continental or global scales as it does not rely on locality-specific knowledge or datasets.

Metamaterial based Printed Circuit Antenna for Blood Glucose Level Sensing Applications

Due to the urgent need to develop technologies for continuous glucose monitoring in diabetes individuals, a potential research has been applied by invoking the microwave techniques. Therefore, this work presents a novel technique based on a single port microwave circuit, antenna structure, based on Metamaterial (MTM) transmission line defected patch for sensing the blood glucose level in noninvasive process. For that, the proposed antenna is invoked to measure the blood glucose through the field leakages penetrated to the human blood through the skin. The proposed sensor is constructed from a closed loop connected to an interdigital capacitor to magnify the electric field fringing at the patch center. The proposed antenna sensor is found to operate excellently at the first mode, 0.6GHz, with S11 impedance matching less than − 10dB. The proposed sensor performance is tested experimentally with 15 cases, different patients, through measuring the change in the S11 spectra after direct touching to the sensor a finger print of a patient. The proposed sensor is found to be effectively very efficient detector for blood glucose variation with a low manufacturing cost when printed on an FR-4 substrate. The experimental measurements are analyzed mathematically to obtain the calibration equation of the sensor from the curve fitting. Finally, the theoretical and the experimental results are found to be agreed very well with a percentage of error less than 10%.

Design of Microwave Antenna Array for Imaging of Multiphase Flows in Polypropylene Pipes

The oil and gas industry requires accurate sensors to control fluid flow in pipelines during the production process from horizontal and near horizontal wells. The extracted crude oil is usually a multiphase mixture of oil, water, and gas, and the accurate measurement of the ratio of each multiphase within the pipeline is an important parameter to manage wells efficiently by maximizing the hydrocarbons that can be extracted. Various methods have been developed for determining the phase ratio including mechanical, optical, X-ray or gamma ray, ultrasound, nuclear magnetic resonance (NMR), and rarely microwave techniques. However, these methods do not permit the knowledge of the real-time evolution of the phase ratio and are less precise. Here, we propose and develop by simulation two microwave systems, in horizontal and vertical polarizations, to choose the optimal configuration for crude pipeline imaging applications. First, the pipeline containing crude oil was modeled and its thermal and dielectric properties are proposed. Then, the antennas array performances were optimized and assembled to the pipeline. Different numbers of antenna elements were successfully investigated using CST simulation in both vertical and horizontal polarizations to find the optimal number of antenna elements for the pipeline applications.

Synthesis and Antimicrobial, Antiproliferative Evaluation of Novel Quinolone and Conazole Analogues via Conventional and Microwave Techniques

1,2,4-Triazole-3-one (3), acquired from cinnemaldehyde was converted to the corresponding carbox(thio)amides via several steps (6a-c). Their reaction with sodium hydroxide gave the 1,2,4-triazole derivatives (7a-c). Compound 3 treatment with 2-bromo-1-(4-chlorophenyl) ethanone or 2-chloro-1-(2,4-dichlorophenyl)ethanone afforded the compounds 8a,b and by reducing these compounds reduction products were obtained (9a,b). The synthesis of (10a-e) was carried out by the reaction compounds 9a,b with different benzyl chlorides. Then oxadiazol derivative (12) was obtained by ring closure from hydrazide compound 5. Subsequently compounds 3, 7a-c and 12 were treated with various amines in the presence of formaldehyde to yield Mannich bases (11a-e, 14a-e, 13a,b). Microwave-assisted and conventional techniques were utilized for the syntheses. The structures of newly synthesized compounds were illuminated by spectroscopic methods. Their antimicrobial (MIC method), and anticancer activities (Abay’s method) were examined. Results showed that most of the compounds exhibited good antimicrobial activities. Especially compounds 14a-e which is a mannich base showed very good antitubercular activity against Mycobacterium smegmatis compared with Streptomycin standard drug. Also compounds 8a and 9b have been found to have strong antiproliferative effects on the HeLa cervical cancer cells and also these compounds did not have cytotoxic effect on normal cell.