Soft X-ray visualization of the liquid water transport within the cracks of micro porous layer in PEMFC

2011 ◽  
Vol 13 (6) ◽  
pp. 638-641 ◽  
Author(s):  
Takashi Sasabe ◽  
Phengxay Deevanhxay ◽  
Shohji Tsushima ◽  
Shuichiro Hirai
Author(s):  
Takashi Sasabe ◽  
Shohji Tsushima ◽  
Shuichiro Hirai

To observe the liquid water distribution in porous layers of an operational Proton Exchange Membrane Fuel Cell (PEMFC) with high spatial and temporal resolution, Laboratory-based soft X-ray microscopy has developed. This system can generate low energy X-ray in the soft X-ray range, and maximum sensitivity towards water is achieved. A point X-ray source with a diameter of less than 1.0 μm and the improved detector optics contribute to realize a spatial resolution of 500 nm and a temporal resolution of 1.0 sec/frame. In addition, in-plane and through-plane observations of an operational PEMFC were carried out. In the in-plane observation test, non-uniform distribution of liquid water in the plane of the catalyst layer was observed, and the importance of appropriate design of the catalyst layer to liquid water transport phenomena was suggested. In the through-plane observation test, liquid water discharge behavior near under the rib area was observed, and the importance of channel wall wettability to liquid water transport phenomena was also suggested.


Author(s):  
Luis Breziner ◽  
Peter Strahs ◽  
Parsaoran Hutapea

The objective of this research is to analyze the effects of vibration on the performance of hydrogen PEM fuel cells. It has been reported that if the liquid water transport across the gas diffusion layer (GDL) changes, so does the overall cell performance. Since many fuel cells operate under a vibrating environment –as in the case of automotive applications, this may influence the liquid water concentration across the GDL at different current densities, affecting the overall fuel cell performance. The problem was developed in two main steps. First, the basis for an analytical model was established using current models for water transport in porous media. Then, a series of experiments were carried, monitoring the performance of the fuel cell for different parameters of oscillation. For sinusoidal vibration at 10, 20 and 50Hz (2 g of magnitude), a decrease in the fuel cell performance by 2.2%, 1.1% and 1.3% was recorded when compared to operation at no vibration respectively. For 5 g of magnitude, the fuel cell reported a drop of 5.8% at 50 Hz, whereas at 20 Hz the performance increased by 1.3%. Although more extensive experimentation is needed to identify a relationship between magnitude and frequency of vibration affecting the performance of the fuel cell as well as a throughout examination of the liquid water formation in the cathode, this study shows that sinusoidal vibration, overall, affects the performance of PEM fuel cells.


2021 ◽  
Vol 507 ◽  
pp. 230285
Author(s):  
Hiroshi Naito ◽  
Kenta Ishikawa ◽  
Takashi Sasabe ◽  
Shuichiro Hirai ◽  
Toshihiro Tanuma

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