Robust ultrathin nanoporous MOF membrane with intra-crystalline defects for fast water transport

Rational design of high-performance stable metal–organic framework (MOF) membranes is challenging, especially for the sustainable treatment of hypersaline waters to address critical global environmental issues. Herein, a molecular-level intra-crystalline defect strategy combined with a selective layer thinning protocol is proposed to fabricate robust ultrathin missing-linker UiO-66 (ML-UiO-66) membrane to enable fast water permeation. Besides almost complete salt rejection, high and stable water flux is achieved even under long-term pervaporation operation in hash environments, which effectively addresses challenging stability issues. Then, detailed structural characterizations are employed to identify the type, chemical functionality, and density of intra-crystalline missing-linker defects. Moreover, molecular dynamics simulations shed light on the positive atomistic role of these defects, which are responsible for substantially enhancing structural hydrophilicity and enlarging pore window, consequently allowing ultra-fast water transport via a lower-energy-barrier pathway across three-dimensional sub-nanochannels during pervaporation. Unlike common unfavorable defect effects, the present positive intra-crystalline defect engineering concept at the molecular level is expected to pave a promising way toward not only rational design of next-generation MOF membranes with enhanced permeation performance, but additional water treatment applications.

Water and Salt Transports in the Hengsha Channel of Changjiang Estuary

In a multilevel bifurcated estuary, the channels between the bifurcated branches play important roles in the exchanges of water and salt. In the Changjiang Estuary, the Hengsha Channel (HC) connects the North Channel (NC) and the North Passage (NP). In this paper, based on a two-way nesting unstructured quadrilateral grid, finite-differencing, three-dimensional estuarine and coastal ocean model, the tidal and seasonal variations in the water and salt transports in the HC were simulated, and their dynamic mechanism was analyzed. The residual water and salt transports in the HC both flow southward from the NC to the NP. In wet season, the residual water transport in the HC is 677 m3/s during neap tide and 245 m3/s during spring tide, and the residual salt transport is 0. In dry season, the residual water and salt transports in the HC are 1278 m3/s and 0.38 t/s during neap tide, respectively, and 1328 m3/s and 12.61 t/s during spring tide. Affected by the northerly wind and the southeastward baroclinic gradient force, the water and salt fluxes in dry season are much larger than those in wet season. The dynamic mechanism responsible for the water transport in the HC was numerically simulated and analyzed.

Model development and prediction of anti-icing longevity of asphalt pavement with salt-storage additive

This study established a systematic simulation framework to predict the anti-icing longevity of a thin overlay of asphalt pavement with salt-storage additive (APSSA). The water and chloride transport in the overlay when subjected to varying precipitation, temperature, thermal cracking, and fatigue cracking over time were modeled using a Finite Element Method based software. The simulation included two parts: water transport followed by chloride transport. Water transport that obeys the law of conservation of mass was modeled using the phase transport in porous media (phtr) interface of COMSOL, while chloride transport based on Fick’s second law was modeled with the transport of diluted species (tds) interface. The simulation results show that the anti-icing function of a 16-mm thick overlay was fully effective in 2 years and 5 years for the minimum pavement temperature above -3.4 °C and -2.4 °C, respectively. These two pavement temperatures are equivalent to 97.4-percentile and 96.3-percentile of historical hourly pavement temperature near Pullman, Washington. Graphical abstract

Characterization and modelling of air humidification in Fuel Cell System for transport sector

A model for the physical description of water transport through steady-state permeation and dynamic sorption within perfluoro-sulfonic acid (PFSA) membranes has been developed. A broad experimental campaign is conducted on several membranes, belonging to Aquivion class, varying both in thickness and equivalent weight (EW). The experimental data have been used to calibrate and validate water transport model and to find correlations for mass-transfer properties in low-EW PFSA membranes that describe consistently both water vapor permeation and sorption. It has been possible to identify individual contributions to mass transport resistance and to determine the optimal configuration and materials of a full-scale counter-flow membrane humidifier under a set of specific operating conditions.