Thermodynamics and separation factor of uranium from lanthanum in liquid eutectic gallium-indium alloy/molten salt system

2014 ◽  
Vol 145 ◽  
pp. 81-85 ◽  
Author(s):  
V. Smolenski ◽  
A. Novoselova ◽  
A. Osipenko ◽  
A. Maershin
Keyword(s):  
Molten Salt ◽  
Separation Factor ◽  
Salt System ◽  
Molten Salt System

scholarly journals Thermodynamics and Separation Factor of Uranium from Fission Products in “Liquid Metal-Molten Salt” System

2018 ◽  
Author(s):  
Valeri Smolenski ◽  
Alena Novoselova ◽  
Alexander Bychkov ◽  
Vladimir Volkovich ◽  
Yana Luk’yanova ◽  
...  
Keyword(s):  
Liquid Metal ◽  
Molten Salt ◽  
Separation Factor ◽  
Fission Products ◽  
Salt System ◽  
Molten Salt System

Molecular Dynamics Simulation Study of the Effect of Ni, Fe, Cu on Cryolite Molten Salt System 78% Na3AlF6-9.5%AlF3-5.0%CaF2-7.5%-Al2O3

2021 ◽  
Vol 1026 ◽  
pp. 39-48
Author(s):  
Han Bing He ◽  
Yu Si Wang ◽  
Ze Xiang Luo ◽  
Jing Zeng
Keyword(s):  
Molecular Dynamics ◽  
Diffusion Coefficient ◽  
Molten Salt ◽  
Diffusion Mechanism ◽  
Research Work ◽  
Dynamics Simulation ◽  
Salt System ◽  
Electrolyte System ◽  
Aluminum Composite ◽  
Molten Salt System

The effect of different additives Ni, Fe, Cu on the structure and properties of electrolyte system 78% Na3AlF6- -9.5%AlF3-5.0%CaF2-7.5%Al2O3 at 1200K and 1.01Mpa was studied by molecular dynamics method. The radial distribution function, coordination number, diffusion coefficient, conductivity, and viscosity of the system were discussed in detail. The results demonstrated that the order of the self-diffusion coefficient of ions in the electrolyte system is: Na+ > F- > O2- > Ca2+ >Al3+. The addition of Ni and Fe connected the free aluminum composite ion groups in the system through fluorine bridges, which enhanced the interaction between Al3+ and Al3+. The addition of Cu weakened the interaction between Al3 + and Al3+ and the F-. The interaction between Al3+ and Na+, [AlF7]4- ionic groups might appeared in the melt system. After adding NiO, Fe2O3, and Cu, the electrical conductivity of the system increased, and the viscosity decreased. The research work revealed the influence of Ni, Fe, Cu on the ion existence form, mobility, inter-ion interaction and diffusion mechanism of cryolite molten salt system, which has important guiding significance for aluminum electrolysis production.

First-principles molecular dynamics investigation on KF-NaF-AlF3 molten salt system

2019 ◽  
Vol 730 ◽  
pp. 587-593 ◽  
Author(s):  
Hui Guo ◽  
Jie Li ◽  
Hongliang Zhang ◽  
Tianshuang Li ◽  
Jiawei Luo ◽  
...  
Keyword(s):  
Molecular Dynamics ◽  
Molten Salt ◽  
First Principles ◽  
Salt System ◽  
Molten Salt System ◽  
First Principles Molecular Dynamics

Effect of Na3WO3F3 Content on the Liquidus Temperature of NaCl-KCl-Na3WO3F3 Molten Salt System

2014 ◽  
Vol 908 ◽  
pp. 159-162
Author(s):  
Jie Li ◽  
Yang Pei ◽  
Ya Bin Liu ◽  
Yun Gang Li
Keyword(s):  
Thermal Analysis ◽  
Differential Thermal Analysis ◽  
Molten Salt ◽  
Liquidus Temperature ◽  
Eutectic Composition ◽  
Eutectic Temperature ◽  
Salt System ◽  
Molten Salt System

The liquidus temperature of molten salt NaCl-KCl-Na3WO3F3 system was measured by differential thermal analysis. The results show that in the molten salt system when XNaCl:XKCl=1:1, XNa3WO3F3<0.6 the liquidus temperature decreased with increase of Na3WO3F3 content; when XNaCl:XKCl=1:1, XNa3WO3F3> 0.6 the liquidus temperature increased with the increase of Na3WO3F3 content; the eutectic temperature is 612.9 °C, the eutectic composition is XNaCl=0.2, XKCl=0.2, XNa3WO3F3=0.6.

scholarly journals Transmutation and inventory analysis in an ATW molten salt system

1995 ◽  
Author(s):  
J. E. Sisolak ◽  
M. T. Truebenbach ◽  
D. L. Henderson
Keyword(s):  
Molten Salt ◽  
Salt System ◽  
Inventory Analysis ◽  
Molten Salt System

The AlF3BaF2NaF molten salt system: calorimetric investigations and modelling

1995 ◽  
Vol 262 ◽  
pp. 45-54 ◽  
Author(s):  
P. Peretz ◽  
G. Hatem ◽  
M. Gaune-Escard ◽  
M. Hoch
Keyword(s):  
Molten Salt ◽  
Salt System ◽  
Calorimetric Investigations ◽  
Molten Salt System

Activities of PbCl2 in the K+, Pb2+/Cl-,SO42- reciprocal molten salt system

1976 ◽  
Vol 29 (9) ◽  
pp. 2069
Author(s):  
RG Anthony ◽  
H Bloom
Keyword(s):  
Molten Salt ◽  
Vapour Pressure ◽  
Reasonable Agreement ◽  
Solution Model ◽  
Salt System ◽  
Ionic Solution ◽  
Pressure Method ◽  
Molten Salt System

Activities of PbCl2 in the molten system K2SO4+PbCl2 have been measured at 1012 K by a transpiration vapour pressure method. Values of PbCl2 activities are calculated from the conformal ionic solution model (CIS), the result being in reasonable agreement with experimentally measured values. Results obtained may therefore be summarized by the CIS equation APbCl2 = xpb(xcl)2exp[0.2405/T)(X?k)2{-3285-X?pb(11564+2032(3X?k-1))}] where Xi, X?t are ion fractions and equivalent ion fractions respectively.

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