Effect of Turbulence On Forced Ignition of Jet-A/Air Mixtures

Consistent ignition of reactive mixtures in turbulent conditions continues to be a challenge, particularly for large, multi-component fuels. Prior work has shown that turbulence can affect ignition parameters such as flame speed, mixture temperature, and minimum ignition energy. However, these works have primarily considered small, single-component fuels. This work studies the effect of turbulence on forced ignition of jet-A/air mixtures with f between 0.3 and 0.7. The ignition probability of these mixtures was measured for bulk velocities between 5 and 7 m/s and turbulence intensities between 3% and 9%. A FLIR SC6700 infrared camera was used to measure the radiation intensity emitted by the flame kernels. Increases in turbulence intensity between 3% and 4% cause the probability of ignition to generally increase. This increase is attributed to the negative flame stretch that develops as a result of the turbulence. This observation is significant because it shows that turbulence can facilitate ignition for jet-A/air mixtures. In contrast, increasing turbulence beyond 5% causes ignition probabilities to decrease. This reduction occurs due to the increased role of heat diffusion and the associated reduction in kernel temperature. The sensitivities of ignition behavior to turbulence intensity and fuel chemistry are reasonably captured using the Peclet number. Further agreement in ignition behavior is achieved by considering Pe/TI2. Ignition probability data for two additional fuels were compared using Pe/TI2. Reasonable agreement within a 95% confidence interval was observed for CH4 mixtures but not for C3H8 mixtures.

Synthesis, DFT calculations and optical nonlinear properties of two derived Schiff base compounds from ethyl-4-amino benzoate

Two Schiff base compounds viz., Ethyl (E)-4-((3-ethoxy-2-hydroxybenzylidene)amino)benzoate(EHB) and Ethyl (E)-4-(((2-hydroxynaphthalen-1-yl)methylene)amino)benzoate(ENB) are synthesized by condensation of ethyl-4-amino benzoate with 2-hydroxy-3-ethoxy benzaldehyde and 2-hydroxy-1-naphthaldehyde. The two compounds are studied and identified by FT-IR, UV-visible, Mass, 1H-NMR and 13C-NMR spectroscopies. The nonlinear refractive index (NRI) of the two compounds are determined, for ENB compound via the diffraction ring patterns (DRPs) and the Z-scan and via Z-scan for the EHB compound, using continuous wave (cw) low power laser beam, and founds of the order of 10-7 cm2/W due to the first technique and 10-8 cm2/W due to the second technique. The optical limiting (OLg) property of both compounds is studied too with OLg thresholds of 16.5 mW and 11 mW for the compounds EHB and ENB respectively, which makes these two compounds as candidates to be used as an optical limiter (OLr). The DRPs are numerically simulated based on the theory of Fresnel-Kirchhoff with reasonable agreement compare to the experimental findings.

Agreement between oscillometric and direct blood pressure measurements in anesthetized captive chimpanzees (Pan troglodytes)

OBJECTIVE To evaluate the level of agreement (LOA) between direct and oscillometric blood pressure (BP) measurements and the ability of oscillometric measurements to accurately detect hypotension in anesthetized chimpanzees (Pan troglodytes). ANIMALS 8 captive, adult chimpanzees. PROCEDURES During prescheduled annual examinations, each chimpanzee underwent general anesthesia and patient monitoring for their examination, echocardiography for a concurrent study, and measurement of direct BP with the use of tibial artery catheterization and oscillometry with the use of a cuff placed around a brachium and a cuff placed around the second digit of the contralateral forelimb for the present study. Bland-Altman plots were generated to compare results for direct and oscillometric BP measurements. Mean bias and 95% LOAs were calculated for oscillometric measurements of systolic arterial pressure (SAP), diastolic arterial pressure (DAP), and mean arterial pressure (MAP) for each cuff site. Sensitivity and specificity in detecting hypotension were also determined for each cuff site. RESULTS There were 74 paired direct and brachial oscillometric measurements of each, SAP, MAP, and DAP and 66 paired direct and digit oscillometric measurements of each, SAP, MAP, and DAP. Only brachial oscillometric measurements of MAP had adequate sensitivity (78%) and specificity (95%) to accurately detect hypotension, and this technique also had the least mean bias (0.8 mm Hg; 95% LOA, –29 to 31 mm Hg). CONCLUSIONS AND CLINICAL RELEVANCE Results indicated that brachial oscillometric measurement of MAP provided reasonable agreement with tibial arterial direct MAP measurement and performed well in diagnosing hypotension in anesthetized chimpanzees.

Spectral Fourier-microscopy of the periodic structures based on Ge2Sb2Te5

The method of spectral Fourier microscopy was used to study the reflection spectra with an angular resolution of submicron periodic gratings based on amorphous and crystalline Ge2Sb2Te5. The form of the dispersion curves of quasi-waveguide modes in the structures under study was established. The experimental data were compared with the calculations of dispersion curves in synthesized diffraction gratings. Reasonable agreement between theoretical and experimental data was obtained.

Directional dependency of electronic stopping in nickel, projectile’s excited charge state and momentum transfer

We studied the directional dependency of electronic stopping power of swift light ions in nickel using real-time time-dependent density functional theory. We report a variation of electronic stopping for moving ions as the projectile probes different electronic densities of the host material. These results show that while the predicted magnitude stays in reasonable agreement with experiment, for $$v > 2$$ v > 2 . a.u. simulating only low index crystallographic directions is not enough to sample the experimental average values. The ab initio simulations give us access to microscopic quantities, such as non-adiabatic forces, momentum transfer and transient excited state charges of the projectile and host ions, which are not available through other methods. We report these quantities for the first time.

Design and SAR assessment of three compact 5G antenna arrays

In this paper three different multi stub antenna arrays at 27–29.5 GHz are designed. The proposed antenna arrays consist of eight single elements. The structure of feeding parts is the same but the radiation elements are different. The feeding network for array is an eight way Wilkinson power divider (WPD). To guarantee the simulation results, one of the proposed structures is fabricated and measured (namely the characteristics of S11, E-, and H-plane patterns) which shows acceptable consistency with measurement results. The simulation results by CST and HFSS show reasonable agreement for reflection coefficient and radiation patterns in the E- and H- planes. The overall size of the proposed antenna in maximum case is 29.5 mm × 52 mm × 0.38 mm (2.8 $${{\varvec{\lambda}}}_{0}$$ λ 0 × 4.86$${{\varvec{\lambda}}}_{0}$$ λ 0 × 0.036$${{\varvec{\lambda}}}_{0}$$ λ 0 ). Moreover, for Specific Absorption Rate (SAR) estimation, a three-layer spherical human head model (skin, skull, and the brain) is placed next to the arrays as the exposure source. The simulation results show that the performance of proposed antennas as low-SAR sources makes them ideal candidates for the safe usage and lack of impact of millimeter waves (mmW) on the human health. In all three cases of SAR simulations the value of SAR1g and SAR10g are below the standard limitations.

An overview of thermotransport in fluorite-related ionic oxides

In this overview, we summarize the phenomenon of thermotransport (the close coupling of mass transport and heat transport) in two fast ion conductors: yttria-doped zirconia and gadolinia-doped ceria. We focus on two recent molecular dynamics calculations using the Green-Kubo formalism. We show that the Onsager thermotransport cross coefficient (mass-heat coupling) is negative, meaning that oxygen ions would drift, in principle, to the hot side in a temperature gradient. Simulation results presented in this overview show reasonable agreement with available experimental data for thermal conductivity. Results of this study suggest that the coupling between mass and heat transport in oxygen ion electrolytes could have significant effect for practical applications.

Critical 1- and 2-point spin correlations for the O(2) model in 3d bounded domains

We study the critical properties of the 3d O(2) universality class in bounded domains through Monte Carlo simulations of the clock model. We use an improved version of the latter, chosen to minimize finite-size corrections at criticality, with 8 orientations of the spins and in the presence of vacancies. The domain chosen for the simulations is the slab configuration with fixed spins at the boundaries. We obtain the universal critical magnetization profile and two-point correlations, which favorably compare with the predictions of the critical geometry approach based on the Yamabe equation. The main result is that the correlations, once the dimensionful contributions are factored out with the critical magnetization profile, are shown to depend only on the distance between the points computed using a metric found solving the corresponding fractional Yamabe equation. The quantitative comparison with the corresponding results for the Ising model at criticality is shown and discussed. Moreover, from the magnetization profiles the critical exponent η is extracted and found to be in reasonable agreement with up-to-date results.

A Modified General Diode Equation

The general diode equation or the non-ideal diode equation is the foundation of circuit models of active devices for the past several decades. Apart from the effect of p-n junction, this equation also accounts for the series bulk resistance of a diode. Despite a reasonable agreement of the equation with measured IV characteristics, it is shown here that the equation is incompatible with basic theories of circuits and systems. Therefore, a modification in the equation is proposed to remove this incompatibility. This modified equation leads to a compact model of a p-n junction diode that has an excellent agreement with the measured IV characteristics.

First-Principles Study of ZnIn2Te4 and HgIn2Te4 Defect-Chalcopyrite Semiconductors Under Different Pressures: Electronic, Elastic, And Optical Properties

First-principle calculations of electronic, elastic, and optical properties for ZnIn2Te4 and HgIn2Te4 defect-chalcopyrite semiconductors have been performed using local density approximation (LDA). Computed energy bandgaps are 1.398 eV and 1.101 eV, respectively, for ZnIn2Te4 and HgIn2Te4, which show the indirect bandgaps behavior. Elastic parameters and Debye temperature have also been investigated at 0, 5, 10, 13, and 14 GPa pressures. Calculated results indicate that both semiconductors are covalent in nature at 0 GPa and become ionic afterward. Optical parameters have also been examined under 0, 5, 10, and 13 GPa in the energy span of 0 eV to 15 eV. The calculated values indicate that these semiconductors are mechanically stable up to 13 GPa and become unstable at 14 GPa. The Calculated values of all parameters are compared with the available experimental and reported values at 0 GPa. A reasonable agreement has been obtained between them. The values of these parameters at 5, 10, 13, and 14 GPa pressures are reported for the first time.