Optimized solvothermal synthesis of LiFePO4 cathode material for enhanced high-rate and low temperature electrochemical performances

2017 ◽  
Vol 258 ◽  
pp. 1149-1159 ◽  
Author(s):  
Xiaopeng Huang ◽  
Keyu Zhang ◽  
Feng Liang ◽  
Yongnian Dai ◽  
Yaochun Yao
2011 ◽  
Vol 14 (3) ◽  
pp. 147-152 ◽  
Author(s):  
Borong Wu ◽  
Ying Zhang ◽  
Ning Li ◽  
Chunwei Yang ◽  
Zhaojun Yang ◽  
...  

F-doped LiFePO4/C cathode materials were synthesized by two-step solid-state reaction route. The F-doped LiFePO4/C increases the intrinsic conductivity, the diffusion of lithium ions, also improves the high-rate and low-temperature performances of LiFePO4. The SEM images reveal some small morphology changes of the two kinds of the materials, so the improved properties may not due to grain size changes but crystal structure changes. The F-doped material has a higher capability at low temperature. At -20°C, with the rate of 0.5C, the discharge capacity was 82mAhg-1, higher than that of undoped material(65mAhg-1) and the result is better than the previous study[17](65mAhg-1 at the rate of 0.3C), and the disparity would enlarge with the rate increased. The CV plots indicate that the doped material reveals less degree of polarization. F-doping sample improves the electrical conductivity of material, accelerating the process of Li+ deintercalation, therefore, improving the electrochemical performances at low temperature.


2013 ◽  
Vol 114 ◽  
pp. 259-264 ◽  
Author(s):  
Xu Yang ◽  
Yunlong Xu ◽  
Huang Zhang ◽  
Yong’an Huang ◽  
Qiong Jiang ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (93) ◽  
pp. 76352-76355 ◽  
Author(s):  
Xinchuan Du ◽  
Gang Huang ◽  
Yuling Qin ◽  
Limin Wang

GO/V2O5 composites prepared from a solvothermal reaction exhibited greatly enhanced electrochemical performances as a cathode material for rechargeable magnesium batteries.


2010 ◽  
Vol 16 (1) ◽  
pp. 1-8 ◽  
Author(s):  
Jun Ma ◽  
Baohua Li ◽  
Hongda Du ◽  
Chengjun Xu ◽  
Feiyu Kang

2011 ◽  
Vol 509 (41) ◽  
pp. 10161-10166 ◽  
Author(s):  
Yuehui Yin ◽  
Mingxia Gao ◽  
Jilai Ding ◽  
Yongfeng Liu ◽  
Lukai Shen ◽  
...  

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